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METHOD FOR PRODUCING ELONGATED STRUCTURES SUCH AS FIBERS FROM POLYMER SOLUTIONS BY STRAINING FLOW SPINNING

机译:通过应变流纺从聚合物溶液中生产纤维等长结构的方法

摘要

A method of molecular self-assembly is disclosed using two interacting streams that are allowed to interact and are subsequently forced through an orifice. A first stream of a dope solution of polymer molecules is extruded out of a capillary. The dope stream is surrounded by a focusing fluid which is miscible with the dope solution. The interaction between the jet of dope solution and surrounding focusing fluid creates hydrodynamic stretching and allows for extracting solvent from the dope solution. Concentrated polymers within the solution at stretched regions of the jet interact, and finally self-assembly takes place after the fluids are forced through the outlet of a converging nozzle. The formation of the structure can be optionally completed in a coagulating space. The structures thus obtained such as fibers or threads can be wound onto a mandrel.
机译:公开了一种分子自组装的方法,其使用两个相互作用的流,该两个相互作用的流被允许相互作用并且随后被迫通过孔口。聚合物分子的涂料溶液的第一流从毛细管中挤出。浓液流被可与浓液溶液混溶的聚焦流体包围。浓液溶液的射流与周围的聚焦流体之间的相互作用产生了流体动力拉伸,并允许从浓液中提取溶剂。溶液中的浓缩聚合物在射流的拉伸区域相互作用,最后在流体被迫通过会聚喷嘴的出口后发生自组装。结构的形成可以任选地在凝结空间中完成。如此获得的结构,例如纤维或线,可以缠绕在心轴上。

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