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METHOD FOR PREPARING PRECURSOR OF NICKEL-COBALT-ALUMINUM TERNARY CATHODE MATERIAL, CATHODE PLATE, AND LITHIUM ION BATTERY
METHOD FOR PREPARING PRECURSOR OF NICKEL-COBALT-ALUMINUM TERNARY CATHODE MATERIAL, CATHODE PLATE, AND LITHIUM ION BATTERY
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机译:镍钴铝三元阴极材料,阴极板和锂离子电池前体的制备方法
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摘要
The present application provides a method for preparing precursor of nickel-cobalt-aluminum ternary cathode material, comprising steps of: 1) mixing a nickel salt solution, a cobalt salt solution, and an aluminum salt solution at a molar ratio of Ni:Co:Al=(0.6-0.9):(0.05-0.3):(0.01-0.1) to obtain a first mixture; 2) adding the first mixture into ammonia water, stirring, and adjusting pH by an alkaline solution to obtain a second mixture with a pH≥12; 3) adding an appropriate amount of additive to the second mixture, stirring, and ageing for 10-24 h to obtain a colloid; 4) washing the colloid and concentrating by centrifugation to obtain a gel; 5) drying the gel at 200-300° C. for 4-8 h, and sintering at 1100-1600° C. for 3-6 h to obtain a precursor of nickel-cobalt-aluminum ternary cathode material. The present application also provides a cathode plate and a lithium ion battery including the same.
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机译:本申请提供一种制备镍钴铝三元阴极材料前体的方法,其包括以下步骤:1)以Ni:Co:摩尔比混合镍盐溶液,钴盐溶液和铝盐溶液: Al =(0.6-0.9):( 0.05-0.3):( 0.01-0.1)以获得第一混合物; 2)将第一混合物加入氨水中,搅拌,并用碱性溶液调节pH值,得到pH≥12的第二混合物。 3)在第二混合物中加入适量的添加剂,搅拌,老化10-24小时,得到胶体。 4)洗涤胶体,离心浓缩得到凝胶; 5)将凝胶在200-300℃下干燥4-8小时,并在1100-1600℃下烧结3-6小时,以获得镍-钴-铝三元阴极材料的前体。本申请还提供了阴极板和包括该阴极板的锂离子电池。
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