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ZINTL-PHASE THERMOELECTRIC CONVERSION MATERIAL

机译:ZINTL相热电转换材料

摘要

The present invention provides a Zintl-phase thermoelectric conversion material represented by the chemical formula (I):; Mg3+m-aAaB2-c-eCcEe   (I)whereA represents at least one selected from the group consisting of Ca, Sr, Ba, Nb, Zn, and Al;B represents at least one selected from the group consisting of Sb and Bi;C represents at least one selected from the group consisting of Mn, Si, and Cr;E represents at least one selected from the group consisting of Se and Te;m is not less than −0.1 and not more than 0.4;a is not less than 0 and not more than 0.1;c is not less than 0 and not more than 0.1;e is not less than 0.001 and not more than 0.06; andthe Zintl-phase thermoelectric conversion material has a La2O3 crystal structure and an average grain size of not less than 3 micrometers and not more than 70 micrometers.
机译:本发明提供由化学式(I)表示的Zintl相热电转换材料: <?in-line-formulae description =“在线公式” end =“ lead”?> Mg 3 + ma A a B 2-ce < / Sub> C c E e (I)<?in-line-formulae description =“ In-line Formulae” end =“ tail”?> 其中 A表示选自Ca,Sr,Ba,Nb,Zn和Al的至少一种; B表示选自Sb和Bi中的至少一个; C代表选自由锰,硅和铬组成的组中的至少一种; E代表选自由Se和Te组成的组中的至少一种; m不小于-0.1且不大于0 .4; a不小于0且不大于0.1; c不小于0且不大于0.1; e不小于0.001且不大于0.06; Zintl相热电转换材料具有La 2 O 3 晶体结构,并且 平均晶粒尺寸不小于3微米且不大于70微米。

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