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Process for the preparation of functionalized castor oil derivatives of epoxidized castor oil (echo) by ring opening and / or transesterification

机译:通过开环和/或酯交换反应制备环氧化蓖麻油(回声)的功能化蓖麻油衍生物的方法

摘要

This invention relates to the development of processes for the preparation of functionalized castor oil derivatives, namely, open-ring glyceryl ricinoleates, alkylenepoxic ricinoleates and open-ring alkyl ricinoleates with adaptive properties of epoxidized castor oil as raw material. using heterogeneous acid-base catalysts. more particularly, the invention employs two reaction chemicals, namely ring opening and transesterification using amberlyst-15 as a solid acid catalyst for the former and oxides derived from caal-double layer hydroxide (caal-ldh) as a solid base catalyst for the last and combinations of these. In addition, both catalysts are reusable and the products are easily separable after reaction by simple physical processes.
机译:本发明涉及功能化蓖麻油衍生物的制备方法的开发,即具有环氧化蓖麻油作为原料的适应性的开环甘油基蓖麻油酸酯,亚烷基氧蓖麻油酸酯和开环烷基蓖麻油酸酯。使用多相酸碱催化剂。更特别地,本发明采用两种反应化学物质,即开环和酯交换反应,其中使用amberlyst-15作为前者的固体酸催化剂,并使用源自caal双层氢氧化物的氧化物(caal-ldh)作为固体碱催化剂作为最后一种催化剂。这些的组合。另外,两种催化剂都是可重复使用的,并且反应后通过简单的物理方法可以容易地分离产物。

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