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NICKEL AND COBALT RECOVERY PROCESS FROM AN ELUTE USING SOLVENT EXTRACTION

机译:溶剂萃取法从洗脱液中回收镍和钴

摘要

nickel and cobalt recovery process from an eluate employing solvent extraction and nickel or cobalt containing product obtained by such process. The present invention relates to a process comprising the following steps: (a) beneficiation or preparation of nickel and / or cobalt-containing ore, in addition to other base metals; (b) ore leaching: may occur in various forms and combinations; (c) pulp resin: the product obtained from the leaching is subjected to resin treatment following a countercurrent flow, eliminating the solid-liquid separation step; (d) solvent extraction: the eluate obtained after resin elution is subjected to operation in one or more solvent extraction stages for nickel and cobalt separation and one or more stages for purification of nickel-containing raffinate, if necessary; (e) Nickel electrolysis: The raffinate obtained in step (d) or the effluent solution of the previous nickel-containing stage feeds the electrolysis step to obtain the final product as nickel cathode; and (f) cobalt along with some impurities are contained in the solvent re-extraction solution, which should feed a cobalt recovery precipitation unit.
机译:从采用溶剂萃取的洗脱液中回收镍和钴的方法,以及通过这种方法获得的含镍或钴的产品。本发明涉及一种方法,该方法包括以下步骤:(a)除其他贱金属外,对镍和/或含钴矿石进行选矿或制备。 (b)矿石浸出:可能以各种形式和组合发生; (c)纸浆树脂:将来自浸出的产物在逆流之后进行树脂处理,省去了固液分离步骤; (d)溶剂萃取:将树脂洗脱后得到的洗脱液在一个或多个用于镍和钴分离的溶剂萃取阶段和一个或多个用于纯化含镍萃余液的阶段进行操作; (e)镍电解:将步骤(d)中获得的提余液或先前的含镍阶段的流出溶液进料到电解步骤中,以获得作为镍阴极的最终产物; (f)溶剂再萃取溶液中含有钴和一些杂质,应将其送入钴回收沉淀装置中。

著录项

  • 公开/公告号BRPI0701068B1

    专利类型

  • 公开/公告日2018-02-27

    原文格式PDF

  • 申请/专利权人 COMPANHIA VALE DO RIO DOCE;VALE S.A.;

    申请/专利号BR2007PI01068

  • 发明设计人 FLÁVIA DUTRA MENDES;

    申请日2007-04-12

  • 分类号B01J31/08;B01D11/04;B01J41/02;C22B3/04;C22B3/42;C22B23;

  • 国家 BR

  • 入库时间 2022-08-21 12:53:22

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