REGULAR CATALYST FOR SYNTHESIZING OXALATE BY CARBON MONOXIDE GASEOUS-PHASE COUPLING,PREPA RATION METHOD AND USE THEREOF

摘要

pProvided is a monolithic catalyst for synthesizing an oxalate by carbon monoxide (CO) gaseous-phase coupling, a preparation method and the use thereof. In the catalyst, a ceramic honeycomb or a metal honeycomb was used as skeletal carrier, metal oxides were used as a carrier coating, precious metals Pt, Pd, Ir, Rh were used as active ingredients, as well as Fe, Co, Ni were used as additives, wherein the carrier coating accounts for 5 to 50 wt % of the honeycomb carrier the active ingredients of the catalyst account for 0.1 to 5 wt. % of the carrier coating; the additives of the catalyst account for 0.3 to 10 wt. % of the carrier coating; and the atomic ratio of the active ingredients to the additives was 0.1 to 3. the reaction for synthesizing the oxalate was carried out in a fixed bed reactor, wherein, N2 was used as a carrier gas. The volume ratio of N2:CO: Alkyl nitrite was 20-80:5-60:10-40, and the retention time was 0.5-10 s./p[US2013150617A1]