LIGANDS FOR TRANSITION-METAL- CATALYZED CROSS- COUPLINGS, AND METHODS OF USE THEREOF

摘要

pLigands for transition metals are disclosed herein, which may be used in various transition-metal-catalyzed carbon-heteroatom and carbon-carbon bond-forming reactions. The disclosed methods provide improvements in many features of the transition-metal-catalyzed reactions, including the range of suitable substrates, number of catalyst turnovers, reaction conditions, and efficiency. For example, improvements have been realized in transition-metal-catalyzed cross-coupling reactions./p[WO2009076622A2]