首页> 外国专利> New di2-(2,4-dichlorophenoxy)propionates alkano-1,X-bis(decyl dimethylammonium) bis-ammonium ionic liquids, method for obtaining them and applications as plant protection products

New di2-(2,4-dichlorophenoxy)propionates alkano-1,X-bis(decyl dimethylammonium) bis-ammonium ionic liquids, method for obtaining them and applications as plant protection products

机译:新型二[2-(2,4-二氯苯氧基)丙酸酯]链烷-1,X-双(癸基二甲基铵)双铵离子液体,制备方法及作为植物保护产品的应用

摘要

the subject of new ionic liquids are bisamoniowe di [2 - (2,4-dichlorophenoxy) propionates) alkano - 1, x - bis (decylodimetyloamoniowe), of the general formula (2) in which, r - means the carbon chain from 4 to 12 carbon atoms in the alkyl chain.the way they receive is that alkano dibromide - 1, x - bis (decylodimetyloamoniowy) of general formula 1, where r is a carbon chain - from 4 to 12 carbon atoms in the alkyl chain is dissolved in water or alcohol, or mixture of alcohol and water, further undergo reaction with salt disodowu0105, or dipotasowu0105, or dilitowu0105, or diamonowu0105 acid, 2 - (2,4-dichlorophenoxy) propionic acid.in a mole ratio of bromide alkano - 1, x - bis (decylodimetyloamoniowego) to the organic acid salt 2: 1, at a temperature of at least 50 degrees, beneficial use during at least 2 minutes, then odsu0105cza to inorganic by-product, after which the product isolated and dried in a temperature effect 70u00b0c.new bisamoniowe ion liquids containing cations alkano - 1, x - bis (anion decylodimetyloamoniowe) and 2 - (2,4-dichlorophenoxy) propanoic acid are used as plant protection products.
机译:新离子液体的主题为通式(2)的Bisamoniowe di [2-(2,4-二氯苯氧基)丙酸酯)链烷醇-1,x-bis(decylodimetyloamoniowewe),其中,r-表示4的碳链烷基链中有12个碳原子。它们的接收方式是将通式1的链烷二溴化物-1,x-bis(decylodimetyloamoniowywy)(其中r是碳链)-溶解在烷基链中的4至12个碳原子上在水或酒精,或酒精和水的混合物中,进一步与盐二氢碘酸,二异丙醇,二氢二茂酸或二亚甲基now酸,2-(2,4-二氯苯氧基)丙酸反应。在至少50度的温度下,溴化烷烃-1,x-双(癸基二甲酰基亚氨基)相对于有机酸盐2:1的摩尔比,在至少2分钟内有益使用,然后由ods u0105cza转化为无机副产物,然后将产物分离并在70℃的温度下干燥。新的含有阳离子的双磺胺离子液体链烷醇1,x-双(阴离子癸基二甲酰亚氨基)和2-(2,4-二氯苯氧基)丙酸用作植物保护产品。

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