New bis-ammonium ionic liquids with alkyl-1,X-bis(bis(2-hydroxyethyl)octadec-9-en ammonium) or bis(ethane)amino-2,2'-bis(bis(2-hydroxyethyl)octadec-9-en ammonium), or butene-1,4-bis(bis(2-hydroxyethyl)octadec-9-en ammonium) cation, method for obtaining them and applications as herbicides

摘要

the subject of new bis ammonium ionic liquids with kationem alkyl - 1, x - bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy) of general formula 2, where r means alkyl: adapter from four to twelve carbon atoms or buteno - 1,4 bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy) model ogu00f3 lnym 4 or bis (ethane-2,1-diyloxyethane-2,1-diyl) amino - 2,2 '- bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy) of general formula 6.where a - is anion (2,4-dichlorophenoxy) octanowy or (4 - chloro - 2 - metylofenoksy) acetic acid.the subject application is also a way to receive new bisamoniowych ionic liquids containing cation alkyl - 1, x - bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy), which is characterized by the fact that quaternary dibromide alkyl - 1, x - bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy) model general 1 is subjected to the exchange reaction with nitrate or potasowu0105 acid sodium salt (2),4 - dichlorophenoxy) acetic acid or (4 - chloro - 2 - metylofenoksy) acetic acid in a mole ratio of a quaternary salt bisamoniowej to salts of 1: 2, at a temperature of from 25oc to 45u00b0c, favourably 20u00b0c, in an organic solvent from the group of: methanol, ethanol, isopropanol, acetone and butanol, after which rozpusz czalnika organic odsu0105cza are formed inorganic by-productfiltrate of vaporized solvent, and the reaction product is dried at a temperature 70u00b0c favourably.the notification contains also apply new bisamoniowych ionic liquid containing cation alkyl, 1 - x - bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy), bueteno - 1,4 bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy) or bis (ethane-2,1-diyloxyethane-2,1-diyl) amino - 2,2 '- bis (bis (2 - hydroxyethyl) oktadec - 9 - enamoniowy) and anion (2), 4 - dichlorophenoxy) octanowy or (4 - chloro - 2 - metylofenoksy) acetic acid as herbicides.