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Chiral tetra azulene fluorene, its derivatives and method for obtaining chiral tetra azulene fluorene

机译:手性四氮杂芴,其衍生物和获得手性四氮杂芴的方法

摘要

the object of the application is relationship, five, six, seven, eight - tetraazaazuleno [1,8 - b, c] fluorene, model ii as a relationship in the form of enantiomers of chiral axial where: r1, r2, r8,r9 and r10 are the same or different and denote: aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings, alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 c atoms.alkin containing from 2 to 10 c atoms; r3 and r5 - are the same or different and are h, oh, nh2, sh, aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings,alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 atoms c, alkin containing from 2 to 10 atoms c, group of formula iii - r11 (iii)where r11 means aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings, alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 c atoms.alkin containing from 2 to 10 atoms c; group of formula iv, s - r12 (iv), where r12 means aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings,alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 atoms c, alkin containing from 2 to 10 c atoms; the group of formula v, nh - r13 (v), where r13 means aryl containing 1 - 4 rings,heteroaryl containing 1 - 4 rings, alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 atoms c, alkin containing from 2 to 10 atoms c; group of formula vi, n - (r14) 2 (vi),where r14 means aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings, alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 c atoms.alkin containing from 2 to 10 c atoms; - r4 means: h, aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings, alkyl containing from 1 to 10 c atoms.alken containing from 2 to 10 atoms c, alkin containing from 2 to 10 c atoms; - r6 means: h, aryl containing 1 - 4 rings, heteroaryl containing 1 - 4 rings,alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 atoms c, alkin containing from 2 to 10 c atoms; - r7 means: aryl containing 1 - 4 rings,heteroaryl containing 1 - 4 rings, alkyl containing from 1 to 10 c atoms, alken containing from 2 to 10 atoms c, alkin containing from 2 to 10 c atoms.the object of the application is also a way to receive tetraazaazulenofluorenu00f3w chiralnych.
机译:本申请的对象是关系,五,六,七,八-四氮杂azuleno [1,8-b,c]芴,模型ii为手性轴向对映体形式的关系,其中:r1,r2,r8,r9和r 10相同或不同,表示:含1-4个环的芳基,含1-4个环的杂芳基,含1-10个碳原子的烷基,含2-10个碳原子的烯。含2-10个碳原子的醇基; r 3和r 5-相同或不同,并且为h,oh,nh 2,sh,含1-4个环的芳基,含1-4个环的杂芳基,含1-10个碳原子的烷基,含2-10个原子的烯基。 ,含2至10个原子的醇; c,式iii-r11(iii)的基团:其中r11是指含1-4个环的芳基,含1-4个环的杂芳基,含1至10个c原子的烷基,含2至10个碳原子的烷基10 c原子。含2至10个原子的c原子;式iv的基团,s-r 12(iv),其中r 12表示含1-4个环的芳基,含1-4个环的杂芳基,含1至10个碳原子的烷基,含2至10个原子的烯基,含1至4个碳原子的烷基。 2至10个c原子;式v的基团,nh-r13(v),其中r13表示含1-4个环的芳基,含1-4个环的杂芳基,含1-10个碳原子的烷基,含2-10个原子的烯基,含2至10个原子c;式VI的基团,n-(r 14)2(vi),其中r 14表示含1-4个环的芳基,含1-4个环的杂芳基,含1-10个碳原子的烷基,含2-10个碳原子的烯基。含2至10个碳原子的白金; -r4是指:h,含1-4个环的芳基,含1-4个环的杂芳基,含1-10个碳原子的烷基。含2-10个原子的烷基al,含2-10个碳原子的醇; -r6是指:h,含1-4个环的芳基,含1-4个环的杂芳基,含1-10个碳原子的烷基,含2-10个原子的烷基,含2-10个碳原子的烷基; -r 7表示:含1-4个环的芳基,含1-4个环的杂芳基,含1至10个碳原子的烷基,含2至10个原子的烷基,含2至10个碳原子的烷基。也是接收四氮杂氮杂氟手性的方法。

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