Process for conversion of alkanes to the corresponding cycle - mixed alcohol, ketone, assisted by microwave.With hydrogen peroxide and chlorine using the escorpionato complex iron (II) as a catalyst,

摘要

The invenu00c7u00c3o refers to the rapid conversion of cyclo alkanes at corresponding mixtures alcohol, ketone, assisted by microwave, with hydrogen peroxide.Using the chlorine complex of iron (II) with the ligand escorpionato hidrotris (1 - pirazolil) methane 'fecl2u00bbhc (PZ) 3} (PZ = pirazolilo) as the catalyst.This process is very effective and selective, allowing the total income (both alcohol and ketone) by 28% after 60 minutes of inflammatory, and frequencies of catalu00cdticos cycle, i.e."Turnoveru00bb, frequency (TOF), expressed in moles of product per mole of catalyst per hour up to 292 (H - 1.