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SHALE HYDRATION INHIBITION AGENT

机译:页岩水化抑制剂

摘要

Additives that act to control clay swelling in drilled formations without adversely effecting properties of the drilling fluid are comprised of bis-3-aminopropyl ether amine functionalities, a derivative thereof, or mixtures thereof. The amine is derived by bis-cyanoethylation of terminal hydroxyl functionalities and subsequent hydrogenation of the nitrile end groups to bis-3-aminopropyl primary amines. The backbone comprises a di-ethers or polyethers based on: ethylene oxide (EO), propylene oxide (PO), and all potential isomers of butyl di-or polyethers. Such bis-3-aminopropyl ether amines may include, but are not limited to amines with the following formula: H2N-R'-O-(RO)x-R'-NH2 where R' is (CH2)3; and R is: 1.) C2H4, with x being 2-10, or 2.) branched C3H6, with x being 1-17, or 3.) branched or linear C4H8, with x being 1-15, or 4.) linear C6H12, with x being 1, or 5.) cyclohexyl-1,4-dimethyl, with x being 1 and mixtures thereof, including, without limitation, Jeffamines (D, M, or XTJ series polyether amines), potassium chloride, choline chloride, and derivatives including partial acid salts of the amines such as those from mineral acids or carboxylic acids with 1-6 carbons.
机译:用于控制钻井地层中的粘土膨胀而不会不利地影响钻井液性能的添加剂包括双-3-氨基丙基醚胺官能团,其衍生物或它们的混合物。所述胺通过末端羟基官能团的双氰乙基化和随后将腈端基氢化为双-3-氨基丙基伯胺而得到。骨架包含基于以下物质的二醚或聚醚:环氧乙烷(EO),环氧丙烷(PO)和丁基二-或聚醚的所有潜在异构体。这种双-3-氨基丙基醚胺可以包括但不限于下式的胺:H 2 N-R′-O-(RO)x -R′-NH 2其中R′是(CH 2)3;和R为:1.)C2H4,x为2-10,或2.)支链C3H6,x为1-17,或3.)支链或线性C4H8,x为1-15或4.)线性C6H12,x为1或5。)环己基-1,4-二甲基,x为1及其混合物,包括但不限于Jeffamines(D,M或XTJ系列聚醚胺),氯化钾,胆碱氯化物,以及包括胺的部分酸盐的衍生物,例如来自具有1-6个碳的无机酸或羧酸的那些。

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