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HALOGEN-FREE FLAME RETARDANT CAPABLE OF WELL KEEPING PERFORMANCE OF POLYPROPYLENE, AND APPLICATIONS THEREOF

机译:聚丙烯保持良好性能的无卤阻燃剂及其应用

摘要

A halogen-free flame retardant capable of well keeping performance of polypropylene. A method for preparing the halogen-free flame retardant comprises: 1, heating 1,3,5-tris(2-hydroxyethyl)cyanuric acid; 2, enabling 1,3,5-tris(2-hydroxyethyl)cyanuric acid to undergo a polymerization reaction under the action of a catalyst, so as to obtain a 1,3,5-tris(2-hydroxyethyl)cyanuric acid polymer; 3, preparing a 1,3,5-tris(2-hydroxyethyl)cyanuric acid polymer charring agent; and 4, mixing ammonium polyphosphate, a triazine charring agent and the 1,3,5-tris(2-hydroxyethyl)cyanuric acid polymer charring agent to carry out surface treatment, so as to finally obtain the halogen-free flame retardant. In addition, also provided is the halogen-free flame retardant prepared by using the method, for use in the preparation of flame-retardant polypropylene. Properties of the prepared flame-retardant polypropylene are superior to those of traditional flame-retardant polypropylene of an ammonium polyphosphate-triazine charring agent system. The obtained halogen-free flame retardant has better compatibility with polypropylene resin, can be comparable with a bromine-antimony flame-retardant system, is superior to bromine-antimony in terms of flame retardance of glowing filaments, and is environmentally-friendlier and very competitive in cost.
机译:一种无卤阻燃剂,能够很好地保持聚丙烯的性能。一种无卤阻燃剂的制备方法,包括:1,加热1,3,5-三(2-羟乙基)氰尿酸; 2,使1,3,5-三(2-羟乙基)氰尿酸在催化剂的作用下发生聚合反应,得到1,3,5-三(2-羟乙基)氰尿酸聚合物。 3,制备1,3,5-三(2-羟乙基)氰尿酸聚合物炭化剂; 4,混合聚磷酸铵,三嗪炭化剂和1,3,5-三(2-羟乙基)氰尿酸聚合物炭化剂进行表面处理,最终得到无卤阻燃剂。另外,还提供了使用该方法制备的无卤阻燃剂,用于制备阻燃聚丙烯。所制备的阻燃聚丙烯的性能优于聚磷酸铵-三嗪炭化剂体系的传统阻燃聚丙烯的性能。所获得的无卤素阻燃剂与聚丙烯树脂具有更好的相容性,可以与溴锑锑阻燃体系相媲美,就发光丝的阻燃性而言,其优于溴锑,并且对环境友好并且具有很高的竞争力。在成本上。

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