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CATALYTIC GASOLINE DESULFURIZATION METHOD HAVING ALSO OLEFIN SELECTIVE REMOVAL FUNCTION

机译:具有烯烃选择性去除功能的催化汽油脱硫方法

摘要

A catalytic gasoline desulfurization method having also an olefin selective removal function, comprising: when a catalytic gasoline is pre-hydrotreated, cutting into a light fraction, an intermediate fraction, and a heavy fraction; performing a liquid-liquid extraction desulfurization treatment with respect to the intermediate fraction to produce a sulfur-depleted oil and a rich solvent containing a sulfur-rich oil; light fraction back-extracting the rich solvent, using C5 olefin therein to replace a macromolecular acyclic olefin in the sulfur-rich oil, thus gathering together C5 isomeric alkene, a cyclic olefin, and a sulfide in the sulfur-rich oil; performing hydrogenation, olefin reduction, and desulfurization treatments on the heavy fraction together with the sulfur-rich oil removed from the back-extracted solvent, saturating the olefin in the oil, and finally preparing together with the sulfur-depleted oil to produce an all-fraction gasoline. The sulfur content of the catalytic gasoline produced per the method can be reduced to 10 ppm or less, thus ensuring reduced octane loss while reducing the olefin content of the catalytic gasoline.
机译:一种还具有烯烃选择性去除功能的催化汽油脱硫方法,包括:当催化汽油经预加氢处理时,切成轻馏分,中间馏分和重馏分;对中间馏分进行液-液萃取脱硫处理,得到贫硫油和含有富硫油的富溶剂。轻馏分反萃取富溶剂,使用其中的C 5 烯烃代替富硫油中的大分子无环烯烃,从而将C 5 异构烯烃聚在一起环烯烃和富硫油中的硫化物;对重馏分进行加氢,烯烃还原和脱硫处理,再与从反萃取溶剂中除去的富硫油一起饱和,使油中的烯烃饱和,最后与贫硫油一起制备以生产全-馏分汽油。可以将通过该方法生产的催化汽油的硫含量降低至10ppm或更少,从而确保降低的辛烷值损失,同时降低了催化汽油的烯烃含量。

著录项

  • 公开/公告号WO2018090584A1

    专利类型

  • 公开/公告日2018-05-24

    原文格式PDF

  • 申请/专利权人 HEBEI REFINING TECHNOLOGY CO.LTD.;

    申请/专利号WO2017CN84460

  • 发明设计人 HAO TIANZHEN;GAO XUHUI;

    申请日2017-05-16

  • 分类号C10G67;

  • 国家 WO

  • 入库时间 2022-08-21 12:44:06

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