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Crosslinkable polymer compositions for flexible cross-linked cable insulators and methods for making flexible cross-linked cable insulators

机译:用于挠性交联电缆绝缘子的可交联聚合物组合物和制造挠性交联电缆绝缘子的方法

摘要

(a) a polymer blend; And (b) from 0 to less than 40 weight percent of a filler, based on the total weight of the crosslinkable polymer composition, wherein the polymer blend comprises (1) the total weight of the crosslinkable polymer composition (I) a density of less than or equal to 0.93 g / cm 3, (ii) a density of less than 0.2 g / 10 min. , A melt index (I 2 ) at 190 캜; And (iii) a shear discoloration ratio (V0.1 / V100) at 190 占 폚 and 10% strain of less than 8; And (2) from 5 to 90 weight percent of high-pressure polyethylene based on the total weight of the crosslinkable polymer composition; Wherein the ethylene based interpolymer of component (a) is not prepared in a high pressure reactor or process. In addition, the polymer blend has the following characteristics: (i) a shear thinning ratio (V0.1 / V100) of 190 at a temperature of 190 DEG C and 10% strain of at least 5, (ii) (iii) melt strength of at least 4 cent Newton at 190 DEG C, and (iv) flexural modulus of less than 25,000 psi, 2% secant. Such a crosslinkable polymer composition can be used as an insulating layer in a flexible power cable.
机译:(a)聚合物共混物; (b)基于可交联聚合物组合物总重量的0至小于40重量%的填料,其中聚合物共混物包含(1)可交联聚合物组合物总重量(I)的密度小于小于或等于0.93 g / cm 3,(ii)密度小于0.2 g / 10 min。 ,熔融指数(I 2 )在190캜; (iii)在190폚和10%应变下小于8的剪切变色率(V0.1 / V100); (2)基于可交联聚合物组合物总重量的5-90重量%的高压聚乙烯;其中组分(a)的基于乙烯的互聚物不是在高压反应器或方法中制备的。另外,该聚合物共混物具有以下特征:(i)在190℃的温度下剪切稀化比(V0.1 / V100)为190,并且至少5的10%应变。(ii)(iii)熔融190°C时强度至少为4美分牛顿,并且(iv)弯曲模量小于25,000 psi,割线为2%。这样的可交联聚合物组合物可以用作柔性电力电缆中的绝缘层。

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