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POLYMERIZATION SOLUTION CONDUCTIVE POLYMER FILM OBTAINED FROM POLYMERIZATION SOLUTION AND SOLID ELETROLYTIC CAPACITOR

机译:从聚合溶液和固体电解电容器获得的聚合溶液导电聚合物膜

摘要

A polymerization liquid for electrolytic polymerization comprising borodisilic acid and / or a salt thereof as a supporting electrolyte is provided which is capable of suppressing precipitation by hydrolysis of borodisilylic acid ions and supplying a conductive polymer having high heat resistance do. The polymerization solution of the present invention is prepared by mixing a solvent comprising 100 to 80 mass% of water and 0 to 20 mass% of an organic solvent, at least one monomer having a? -Conjugated double bond, and a mixture of borodysalicylic acid and borodisalicylic acid salt And at least one stabilizer selected from the group consisting of nitrobenzene and a nitrobenzene derivative, wherein the content of the stabilizer is at least one selected from the group consisting of Is more than 1/8 mol relative to 1 mol of the supporting electrolyte. A complex of the stabilizer and borodysalicylic acid is formed to inhibit precipitation by hydrolysis of borodisilicylic acid ions.
机译:提供一种用于电解聚合的包含硼二硅酸和/或其盐作为支持电解质的聚合液,其能够抑制由于硼二甲硅酸酸根离子的水解而引起的沉淀并提供具有高耐热性的导电聚合物。通过混合包含100至80质量%的水和0至20质量%的有机溶剂的溶剂来制备本发明的聚合溶液,至少一种具有α2的单体。 -共轭双键,以及硼氢化水杨酸和硼二水杨酸盐的混合物和选自由硝基苯和硝基苯衍生物组成的组中的至少一种稳定剂,其中稳定剂的含量为选自由以下组成的组中的至少一种:相对于1摩尔支持电解质小于1/8摩尔。形成稳定剂和硼氢化水杨酸的络合物,以抑制硼二硅氢酸离子的水解而沉淀。

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