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PRODUCTION METHOD FOR CATALYST MICROPARTICLES AND FUEL CELL CONTAINING CATALYST MICROPARTICLES PRODUCED BY SAID PRODUCTION METHOD

机译:赛义德公司生产的催化剂微颗粒的生产方法以及包含燃料微颗粒的燃料电池

摘要

A method for producing catalyst microparticles exhibiting high activity from the beginning of manufacture, and a fuel cell comprising the catalyst microparticles produced by the production method. Containing particle and a platinum outermost layer covering the palladium-containing particle, wherein the palladium-containing particle and the first solution in which the platinum compound is dissolved are mixed, and at least the surface of the palladium-containing particle surface Forming a first composite comprising palladium and platinum by coating a portion thereof with platinum; The first composite is mixed with a second solution in which the compound is dissolved and at least a part of the surface of the first composite is covered by copper using the copper underpotential deposition method to form a layer containing palladium, To form a second composite; Further, the method for producing catalyst microparticles, wherein the copper in the second composite is replaced with platinum derived from the third solution by mixing the second composite and the third solution in which the platinum compound is dissolved.
机译:从制造开始就生产具有高活性的催化剂微粒的方法,以及包括通过该生产方法生产的催化剂微粒的燃料电池。包含颗粒和覆盖所述含钯颗粒的最外层铂,其中将所述含钯颗粒和溶解有铂化合物的第一溶液混合,并且至少所述含钯颗粒表面形成第一复合材料通过将铂和铂的一部分涂覆铂而包含钯和铂;将第一复合材料与其中溶解有化合物的第二溶液混合,并且使用铜欠电位沉积法将第一复合材料的至少一部分表面用铜覆盖,以形成包含钯的层。此外,通过将第二复合物和溶解有铂化合物的第三溶液混合,将第二复合物中的铜替换为源自第三溶液的铂,以制备催化剂微粒。

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