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POLYUREA COMPOSITION FOR ANTI-CORROSION PROTECTIVE COATING OF STEEL SURFACES

机译:用于钢表面防腐涂层的聚脲组合物

摘要

FIELD: technological processes.;SUBSTANCE: invention relates to a polyurea composition for coatings on a metal surface. Polyurea composition consists of two components of an isocyanate prepolymer based on diphenylmethane diisocyanate and a curable component with active hydrogen atoms of the amino groups. Isocyanate prepolymer further comprises hexamethylene diisocyanate. Curable component comprises an epoxide-modified polyether amine of a molecular weight of 2,000–3,000, a polyetheramine of 400 molecular weight, diethyltoluene diamine, 3,3'-dichloro-4,4'diaminodiphenylmethane and polysulfide polymer with a content of thiol groups of at least 3 %. Mass fraction of the isocyanate groups of the isocyanate prepolymer is 18–20 % and the dynamic viscosity 0.8–2.0 Pa*s at 25±0.1 °C. Amine number of the second component with the active hydrogen atoms is 20–60 mg KOH/g. Ratio of the components of the polyurea composition is, mass parts: 40–50 of modified epoxy polyester, 4–15 of polysulfide polymer, 25–35 of diethyltoluylenediamine, 5–10 of 3,3'-dichloro-4,4'diaminodiphenylmethane, 10–20 of polyetheramine of molecular weight of 400, 0.5 of carbon black or other pigment, 1.0 of fine-dispersed titanium dioxide, 40–60 of trimerized isocyanate HDI and 40–50 of prepolymer based on MDI.;EFFECT: produced polyurea composition allows to obtain coatings on the surface of the metal with improved physical and mechanical properties, and also simplifies the coating process.;1 cl, 3 tbl, 3 ex
机译:聚脲组合物技术领域本发明涉及一种用于金属表面上的涂料的聚脲组合物。聚脲组合物由基于二苯基甲烷二异氰酸酯的异氰酸酯预聚物的两个组分和具有氨基的活性氢原子的可固化组分组成。异氰酸酯预聚物进一步包含六亚甲基二异氰酸酯。可固化组分包括分子量为2,000-3,000的环氧改性聚醚胺,分子量为400的聚醚胺,二乙基甲苯二胺,3,3'-dichloro-4,4'diaminodiphenylmethane和硫醇含量为至少3个 %。异氰酸酯预聚物中异氰酸酯基团的质量分数为18–20%,在25±0.1°C下的动态粘度为0.8–2.0 Pa * s。具有活性氢原子的第二种成分的胺值为20–60 mg KOH / g。聚脲组合物中各成分的比例为质量份:40–50的改性环氧聚酯,4–15的聚硫聚合物,25–35的二乙基甲苯二胺,5–10的3,3'-dichloro-4,4'diaminodiphenylmethane ;分子量为400的聚醚胺10–20,炭黑或其他颜料0.5,细分散的二氧化钛1.0,三聚异氰酸酯HDI 40–60和基于MDI的预聚物40–50;效果:生产的聚脲组成允许在金属表面上获得具有改善的物理和机械性能的涂层,并且还简化了涂层过程。; 1 cl,3 tbl,3 ex

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