首页> 外国专利> NON-AQUEOUS COATING COMPOSITIONS, COATINGS OBTAINED FROM THEM AND WITH IMPROVED ADHESION AND SCRUB RESISTANCE, AND ALSO THEIR APPLICATION

NON-AQUEOUS COATING COMPOSITIONS, COATINGS OBTAINED FROM THEM AND WITH IMPROVED ADHESION AND SCRUB RESISTANCE, AND ALSO THEIR APPLICATION

机译:非水性涂料组合物,由其获得的,具有改善的附着力和耐擦伤性的涂料及其应用

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to non-aqueous compositions of coating materials. Non-aqueous coating composition comprising at least one component containing polyhydroxylic groups, extracted from polyacrylates polyols, mixtures thereof and copolymers of polyacrylates polyols, at least one component containing polyisocyanate groups, at least one catalyst for crosslinking alkoxysilyl units, for the reaction between the hydroxyl and isocyanate groups of the components, and at least one urethane additive (PF) which has at least one perfluoroalkyl group of the formula (I) wherein R1, R2 independently of one another, are H, F and/or CF3, but R1 and R2 both may not mean H, x is 1–20, and at least one silane group of formula (II) wherein G is a hydrolyzable group, X is an organic radical, R3 means alkyl, cycloalkyl, aryl or aralkyl, and s is 0–2, wherein the urethane additive (PF) is prepared by reacting 0.5 to 20 mol. % of the isocyanate groups originally present in the polyisocyanate (PI), with component (Ia), which has at least one perfluoroalkyl group of formula (I) and one group which is reactive with respect to isocyanate groups, and 10–99.5 mol. % of the isocyanate groups initially present in the polyisocyanate (PI) with a component (IIa) which has at least one silane group of the formula (II) and one group that is reactive with isocyanate groups. Multilayer color system using this composition, a method for its preparation and use are also provided. CR13-(CR22)x- (I); -X-Si-R3sG3-s (II).;EFFECT: proposed non-aqueous coating composition makes it possible to obtain films of a coating lacquer with improved adhesion.;15 cl, 4 tbl
机译:涂料的非水组合物技术领域本发明涉及涂料的非水组合物。非水性涂料组合物,其包含至少一种从聚丙烯酸酯多元醇,其混合物和聚丙烯酸酯多元醇的共聚物中提取的含多羟基的组分,至少一种含多异氰酸酯基的组分,至少一种用于使羟基之间的反应交联的烷氧基甲硅烷基的催化剂组分的异氰酸酯基和至少一种具有至少一个式(I)的全氟烷基的氨基甲酸酯添加剂(PF),其中R 1 ,R 2 彼此是H,F和/或CF 3 ,但R 1 和R 2 可能都不表示H,x为1 –20,以及至少一个式(II)的硅烷基团,其中G为可水解基团,X为有机基团,R 3 表示烷基,环烷基,芳基或芳烷基,且s为0–参照图2,其中通过使0.5至20摩尔反应来制备氨基甲酸酯添加剂(PF)。最初存在于多异氰酸酯(PI)中的%的异氰酸酯基,其组分(Ia)具有10–99.5 mol,该组分具有至少一个式(I)的全氟烷基和一个对异氰酸酯基具有反应性的基团。最初存在于具有组分(IIa)的多异氰酸酯(PI)中的异氰酸酯基的%,所述组分(IIa)具有至少一个式(II)的硅烷基和一个可与异氰酸酯基反应的基团。还提供了使用该组合物的多层彩色系统,其制备和使用方法。 CR 1 3 -(CR 2 2 x -(I); -X-Si-R 3 s G 3-s (II).;效果:建议的非水性涂料组合物使得获得具有改善粘合力的涂料漆膜;; 15 cl,4 tbl

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