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Process for producing modified precipitated silica and composition containing modified precipitated silica

机译:制备改性沉淀二氧化硅的方法和包含改性沉淀二氧化硅的组合物

摘要

The object of the present invention is to provide an economical and yet resource-saving method for the rapid and easy production of cheap organically modified silicas, and to provide compositions having high chemical purity containing these silicas. It is to be. The first part of the object is a process for the preparation of a modified precipitated silica, wherein i) the modification comprises An acid; The reaction is carried out in a reaction mixture comprising a compound selected from precipitated silica and / or [SiO4 / 2] starting materials and an organosiliconate as a modifier, the modification reaction being to produce precipitated silica Reaction is carried out during or immediately after the reaction, ii) then the reaction mixture is filtered and washed, and iii) dried if the reaction mixture is needed, an organosiliconate is used as a modifier, an alkoxysilane or an alkali silicon silicic acid The acid salt is achieved by providing the method used as a [SiO4 / 2] starting material. The second part of the object comprises (a) at least 95% by weight of precipitated silica, (b) a carbon content of at least 0.5% by weight, and (c) a combined sodium and potassium content This is achieved by providing a composition characterized in that it is less than 5000 ppm and (d) the sulfur content is less than 2500 ppm. The compositions according to the invention can be used as antiblocking agents in toners or developers as reinforcing fillers in crosslinkable silicone rubber compounds.
机译:本发明的目的是提供一种经济而又节省资源的方法,用于快速和容易地生产廉价的有机改性的二氧化硅,并提供包含这些二氧化硅的具有高化学纯度的组合物。是的。目的的第一部分是制备改性的沉淀二氧化硅的方法,其中i)所述改性剂包括酸;该反应在包含选自沉淀二氧化硅和/或[SiO 4/2]起始原料的化合物和有机硅酸盐作为改性剂的反应混合物中进行,该改性反应是产生沉淀二氧化硅的反应。反应,ii)然后将反应混合物过滤并洗涤,并且iii)如果需要反应混合物干燥,使用有机硅酸盐作为改性剂,烷氧基硅烷或碱金属硅硅酸盐通过提供所使用的方法获得酸盐。作为[SiO4 / 2]的起始原料。该目的的第二部分包含(a)至少95重量%的沉淀二氧化硅,(b)碳含量至少0.5重量%,和(c)钠和钾的总含量。该组合物的特征在于其小于5000ppm,并且(d)硫含量小于2500ppm。本发明的组合物可用作调色剂中的防粘剂或用作可交联的硅橡胶化合物中的增强填料的显影剂。

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