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Method is used to produce the manufacturing method of reactivated catalyst system and ester compounds using reactivating catalyst system

机译:方法用于生产再活化催化剂体系和使用再活化催化剂体系的酯化合物的制造方法

摘要

PROBLEM TO BE SOLVED: To provide, in a method for producing an ester compound using a metal catalyst, a method for greatly reducing a practical cost of the metal catalyst by directly reusing a residue of a catalyst system recovered from a reaction mixture without going through a process of metal recovery and catalyst resynthesis.SOLUTION: Provided is a method for producing a reactivated catalyst system comprising a process of reactivating a recovered catalyst system which is recovered after an ester compound is produced by reacting a compound having at least one unsaturated carbon bond in a molecule with a formate ester in the presence of a catalyst system comprising a ruthenium compound, a cobalt compound, and a halide salt. The process includes treating the recovered catalyst system with a peroxide such as sodium percarbonate or with air.SELECTED DRAWING: None
机译:解决的问题:提供一种使用金属催化剂生产酯化合物的方法,该方法通过不经处理而直接重复使用从反应混合物中回收的催化剂体系的残留物来大大降低金属催化剂的实际成本的方法。解决方案:提供一种生产再活化的催化剂体系的方法,该方法包括使活化的回收催化剂体系的过程再活化的过程,该过程是在酯化合物通过具有至少一个不饱和碳键的化合物反应制备后回收的。在包含钌化合物,钴化合物和卤化物盐的催化剂体系的存在下,与甲酸酯形成分子。该方法包括用过氧化物如过碳酸钠或空气处理回收的催化剂体系。

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