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Use the environment polymer film film of erbium complex

机译:使用环境高分子膜polymer复合膜

摘要

PROBLEM TO BE SOLVED: To provide a metal complex that shows ff emission having a high luminescence quantum yield in a solid state, in a lanthanide metal complex, emits light while maintaining complex formation even when an LB film is formed, and can be applied to the sufficient design of a material for promoting ff emission in an LB film using the lanthanide metal complex and to a polarized light-emitting body achieving stable emission properties and polarizability, and to provide an LB film and a method for manufacturing the same.SOLUTION: A metal complex in which 6 nitrogen atoms are coordinated with or bonded to one lanthanide metal atom is designed and synthesized by introducing a structure including a long alkyl chain in a ligand molecule. As a result, a new metal complex was found which is stable for a long period of time in air and is easy in handling. A monomolecular film comprising the complex according to the present invention and its built-up film (LB film), and the complex are used as emission materials.SELECTED DRAWING: Figure 1
机译:解决的问题:为了提供在固态下具有高发光量子产率的ff发射的金属络合物,在镧系金属络合物中,即使在形成LB膜的情况下也能在保持络合物形成的同时发光并可以应用于使用镧系金属络合物促进LB膜中ff发射的材料的充分设计,并获得实现稳定发射性能和极化性的偏振发光体,并提供LB膜及其制造方法。通过在配体分子中引入包括长烷基链的结构来设计和合成其中6个氮原子与一个镧系金属原子配位或键合的金属配合物。结果,发现了一种新的金属络合物,该络合物在空气中长期稳定并且易于处理。包含根据本发明的配合物及其堆积膜(LB膜)的单分子膜和该配合物用作发光材料。选图:图1

著录项

  • 公开/公告号JP6460739B2

    专利类型

  • 公开/公告日2019-01-30

    原文格式PDF

  • 申请/专利权人 長谷川 美貴;

    申请/专利号JP20140233353

  • 发明设计人 長谷川 美貴;

    申请日2014-11-18

  • 分类号C07D213/40;C09K11/06;C07F5;

  • 国家 JP

  • 入库时间 2022-08-21 12:17:47

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