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Efficient halogen-free flame retardant masterbatch for polypropylene and preparation method and use thereof

机译:聚丙烯用高效无卤阻燃母料及其制备方法和用途

摘要

The present invention provides an efficient halogen-free flame retardant masterbatch for polypropylene, which comprises following raw materials in percentage by weight: 30˜40% of ammonium polyphosphate; 10˜20% of pentaerythritol phosphate; 15˜25% of melamine; 5˜15% of bisphenol A bis(diphenyl phosphate); 10˜30% of microporous polypropylene; 0.1˜1% of pentaerythritol stearate; 0.1˜0.5% of antioxidant 1010; and 0.1˜0.5% of antioxidant 168. Said microporous polypropylene is particles with a size of 3˜5 mm, cell size on a surface of the particle is 10˜100 μm, and cell density is more than 105 cells/cm3. The efficient halogen-free flame retardant masterbatch for polypropylene prepared by the invention has several characteristics of easy dispersing, easy processing, high flame retardant efficiency and low production cost, and it can be widely used in the production of flame retardant polypropylene materials for extrusion, injection molding and membrane blowing.
机译:本发明提供了一种有效的聚丙烯无卤阻燃母料,其包含以下原料,按重量百分比计:30〜40%的聚磷酸铵; 10〜20%的季戊四醇磷酸酯; 15〜25%的三聚氰胺; 5〜15%的双酚A双(磷酸二苯酯); 10〜30%的微孔聚丙烯;季戊四醇硬脂酸酯的0.1〜1%;抗氧化剂1010的0.1〜0.5%;抗氧化剂168和0.1〜0.5%的抗氧化剂。所述微孔聚丙烯为3〜5mm的颗粒,颗粒表面的孔尺寸为10〜100μm,孔密度大于10 5 cells / cm 3 。本发明制备的高效聚丙烯无卤阻燃母料具有分散,易加工,阻燃效率高,生产成本低的几个特点,可广泛用于生产挤出用阻燃聚丙烯材料。注塑和吹膜。

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