i) preparing a plurality of blends of the at least two nucleators wherein each blend contains the same at least two nucleators but in a different weight ratio, wherein the plurality of blends includes one or more blends in which one of the at least two nucleators is a major weight fraction of the blend as well as one or more blends in which the same one of the at least two nucleators is a minor weight fraction of the blend;ii)determining, for each of the blends prepared in step i), a minimum dissolution temperature at which a given concentration of each of the blends becomes completely dissolved in individual samples of the same molten polyolefin resin, wherein the concentration of each of the different blends in the individual samples is substantially the same and below the saturation point in the molten polyolefin resin and the same method for determining the minimum dissolution temperature is used for each blend; andiii) identifying a blend of the at least two nucleators which has a minimum dissolution temperature which is lower than that determined in step ii) for a majority of the plurality of blends."/> METHOD FOR IDENTIFYING A BLEND OF NUCLEATORS USEFUL FOR PREPARING A NUCLEATED POLYOLEFIN MATERIAL
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METHOD FOR IDENTIFYING A BLEND OF NUCLEATORS USEFUL FOR PREPARING A NUCLEATED POLYOLEFIN MATERIAL

机译:鉴定可用于制备核聚烯烃材料的成核剂混合物的方法

摘要

The present invention relates to a method for identifying a blend of nucleators which is advantageous for providing reduced haze in a nucleated polyolefin material compared to blends of the same nucleators having different weight ratios of components. In one aspect, the present invention provides a method for identifying a blend of at least two nucleators having a weight ratio of components that provides reduced haze in a nucleated polyolefin material compared to blends of the same nucleators having different weight ratios of components, wherein each nucleator is soluble in a molten polyolefin resin, said method comprising the steps of:i) preparing a plurality of blends of the at least two nucleators wherein each blend contains the same at least two nucleators but in a different weight ratio, wherein the plurality of blends includes one or more blends in which one of the at least two nucleators is a major weight fraction of the blend as well as one or more blends in which the same one of the at least two nucleators is a minor weight fraction of the blend;ii)determining, for each of the blends prepared in step i), a minimum dissolution temperature at which a given concentration of each of the blends becomes completely dissolved in individual samples of the same molten polyolefin resin, wherein the concentration of each of the different blends in the individual samples is substantially the same and below the saturation point in the molten polyolefin resin and the same method for determining the minimum dissolution temperature is used for each blend; andiii) identifying a blend of the at least two nucleators which has a minimum dissolution temperature which is lower than that determined in step ii) for a majority of the plurality of blends.
机译:本发明涉及一种鉴定成核剂共混物的方法,与具有不同组分重量比的相同成核剂的共混物相比,该方法有利于减少成核聚烯烃材料中的雾度。一方面,本发明提供了一种用于鉴定具有组分重量比的至少两个成核剂的共混物的方法,与具有不同组分重量比的相同成核剂的共混物相比,该成核聚烯烃材料的雾度降低了,其中每个成核剂可溶于熔融的聚烯烃树脂中,所述方法包括以下步骤: i)制备至少两个成核剂的多个共混物,其中每个共混物包含相同的至少两个成核剂,但重量比不同,其中多个共混物包括一种或多种其中一种或多种共混物。至少两个成核剂是混合物的主要重量分数,以及一种或多种混合物,其中至少两个成核剂中的相同一个是混合物的次重量分数; ii)为步骤i)中制备的每种共混物确定最小溶解温度,在该最低溶解温度下,给定浓度的每种共混物完全溶解在相同熔融聚烯烃树脂的各个样品中,其中各个样品中每种不同混合物的浓度基本相同且为熔融聚烯烃树脂的饱和点低,每种共混物的测定最低溶解温度的方法相同。和 iii)标识至少两个成核剂的混合物,该成核剂的最低溶解温度低于步骤ii)中确定的最低溶解温度多个混合中的一个。

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