R1k(C6H4-k)(COOR2)(COOR3)  (1) andan organic compound represented the following general formula (2)R4R5C═C (COOR6)(COOR7)  (2)wherein R1 is a halogen atom or an alkyl group, R2 and R3 are a linear alkyl group, R4 and R5 are independently an atom or group selected from a hydrogen atom, halogen, a linear alkyl group, a branched alkyl group a vinyl group, a linear or branched alkenyl group, a cycloalkenyl group, an aromatic hydrocarbon group, and R6 and R7 are independently a linear alkyl group, a branched alkyl group, a vinyl group, a linear or branched alkenyl group a cycloalkyl group, a cycloalkenyl group, or an aromatic hydrocarbon group."/> Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization
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Method for producing solid catalyst component for olefin polymerization, catalyst for olefin polymerization and a process for propylene polymerization

机译:烯烃聚合用固体催化剂组分的生产方法,烯烃聚合用催化剂和丙烯聚合的方法

摘要

A method for producing a solid catalyst for olefin (co)polymerization includes bringing into contact with each other a magnesium compound, a tetravalent titanium halide compound, an organic compound represented the following general formula (1)R1k(C6H4-k)(COOR2)(COOR3)  (1) andan organic compound represented the following general formula (2)R4R5C═C (COOR6)(COOR7)  (2)wherein R1 is a halogen atom or an alkyl group, R2 and R3 are a linear alkyl group, R4 and R5 are independently an atom or group selected from a hydrogen atom, halogen, a linear alkyl group, a branched alkyl group a vinyl group, a linear or branched alkenyl group, a cycloalkenyl group, an aromatic hydrocarbon group, and R6 and R7 are independently a linear alkyl group, a branched alkyl group, a vinyl group, a linear or branched alkenyl group a cycloalkyl group, a cycloalkenyl group, or an aromatic hydrocarbon group.
机译:制备用于烯烃(共)聚合的固体催化剂的方法包括使镁化合物,四价卤化钛化合物,以下通式(1)表示的有机化合物彼此接触。<?in-line-formulae description =“ In-line Formulae” end =“ lead”?> R 1 k (C 6 H 4-k )(COOR 2 )(COOR 3 )(1)和<?in-line-formulae description =“在线公式“ end =“ tail”?>代表以下通式(2)的有机化合物<?in-line-formulae description =“在线公式” end =“ lead”?> R 4 R 5 C═C(COOR 6 < / Sup>)(COOR 7 )(2)<?in-line-formulae description =“ In-line Formulae” end =“ tail”?>其中R 1 是卤素原子或烷基,R 2 和R 3 是直链烷基,R 4 < / Sup>和R 5 独立地是选自氢原子,卤素,直链烷基,支链烷基,乙烯基,直链或支链烯基,环烯基的原子或基团,芳族烃基,R 6和R 7分别独立地为直链烷基,支链烷基,乙烯基,直链或支链烯基,环烷基基,环烯基或芳族烃基。

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