Photopolymerizable compositions for forming a cosmetic nail coating or artificial nail and methods of using such compositions. The compositions include (a) at least one rheology modifier; (b) from about 15 wt % to about 80 wt % of one or more (meth)acrylate oligomers; (c) from about 5 wt % to about 60 wt % of one or more (meth)acrylate monomers; and (d) one or more photoinitiators; wherein the at least one rheology modifier is selected in an amount such that the viscosity of the composition is greater than 400,000 centipoise (cps) at 25° C. The compositions may be a liquid or a gel capable of forming an artificial nail or cosmetic nail coating in one application and without being mixed with any additional components.
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