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METAL ORGANIC FRAMEWORK (MOF) STRUCTURED OBJECT AND METHOD

机译:金属有机框架(MOF)结构化的对象和方法

摘要

A method of making a metal organic framework (MOF)-polymer composite material includes forming a homogeneous solution comprising a solvent, a metal salt, a polymer which is soluble in the solvent, and a reactant which can be synthesized to provide an organic linker during formation of a MOF structure, synthesizing the homogeneous solution to crystallize a MOF structure in the homogenous solution to yield the MOF structure distributed in a remainder solution, applying an antisolvent to the remainder solution with the MOF structure distributed in the remainder solution to form a polymer-rich phase, where the MOF structure is integrated into the polymer matrix during forming of the polymer matrix to produce a MOF-polymer composite material. The MOF-polymer composite material can be formed on a substrate to produce a MOF structured object, which can be a membrane, film, or other object.
机译:一种制备金属有机骨架(MOF)-聚合物复合材料的方法,包括形成均质溶液,该均质溶液包括溶剂,金属盐,可溶于该溶剂的聚合物以及可合成以在反应期间提供有机连接基的反应物。形成MOF结构,在均质溶液中合成均相溶液以使MOF结构结晶,以产生分布在剩余溶液中的MOF结构,将抗溶剂施加到剩余溶液中,将MOF结构分布在剩余溶液中以形成聚合物-富相,其中在聚合物基体形成期间将MOF结构整合到聚合物基体中以产生MOF-聚合物复合材料。可以将MOF-聚合物复合材料形成在基底上以产生MOF结构化的物体,该物体可以是膜,膜或其他物体。

著录项

  • 公开/公告号US2019232251A1

    专利类型

  • 公开/公告日2019-08-01

    原文格式PDF

  • 申请/专利权人 GM GLOBAL TECHNOLOGY OPERATIONS LLC;

    申请/专利号US201815880976

  • 发明设计人 ANNE M. DAILLY;FANG DAI;TIMOTHY J. FULLER;

    申请日2018-01-26

  • 分类号B01J20/26;B01J31/16;B01J31/06;B01J35;B01J35/02;B01J37/04;B01J37/03;B01J20/22;B01J20/30;B01J20/28;H01M10/0565;H01M10/052;B01D71/36;B01D69/14;

  • 国家 US

  • 入库时间 2022-08-21 12:08:34

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