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METHOD FOR THE PREVENTION OF THE FORMATION OF SUBSTANCES-CURING AGENTS OF THEIR PRECURSORS IN THE AEROSOL COMPOSITION AND TWO-COMPONENT AEROSOL COMPOSITION

机译:预防气溶胶成分和两种成分的气溶胶成分中前体物质诱因形成的方法

摘要

A method of preventing the formation of hardening substances from their precursors in an aerosol composition suitable for use in an aerosol can for making paints and varnishes, in which an aerosol composition is prepared by adding the following substances to a can: kravoobrazuyuschimi chemicals, including epoxy resin precursor; weak acid and possible solvent; and mixing these chemical-forming chemicals, a weak acid and a possible solvent to form a mixture before or after adding these compounds to a balloon, characterized in that a weak acid (XCOOH) is added in a catalytic amount, the weak acid selected from the group in which weak acids have the value of the dissociation constant pKa, lying in the range from 1.2 to 5.2, in the presence of (free) water and ketone chemical equilibrium between the epoxy resin hardener precursor and epoxy hardeners The resins were shifted towards the formation of precursors of epoxy hardeners according to the general reaction equation (2a): XCOOH + amines hardeners of epoxy resin + ketone → precursor of hardener epoxy resin + water (2a), so that the formation of amine hardeners of epoxy resin from hardeners precursors is prevented epoxy resin, and the precursors of hardeners epoxy resin selected from the group consisting of imine, enamine, Mannich base, aldimine, and mixtures thereof.
机译:一种防止在适用于制造油漆和清漆的气雾罐中的气溶胶组合物中从其前体形成硬化物质的方法,其中,通过向罐中添加以下物质来制备气溶胶组合物:kravoobrazuyuschimi化学物质,包括环氧树脂树脂前体弱酸和可能的溶剂;在将这些化合物加入气球之前或之后,将这些化学形成剂,弱酸和可能的溶剂混合以形成混合物,其特征在于,以催化量加入弱酸(XCOOH),所述弱酸选自在环氧树脂固化剂前体和环氧固化剂之间存在(游离)水和酮化学平衡的情况下,弱酸的解离常数pKa值在1.2到5.2之间的组根据一般反应方程式(2a)形成环氧固化剂的前体:XCOOH +环氧树脂+酮的胺类固化剂→固化剂环氧树脂+水的前体(2a),从而由固化剂形成环氧树脂的胺类固化剂前体是防环氧树脂,而硬化剂环氧树脂的前体选自亚胺,烯胺,曼尼希碱,醛亚胺及其混合物。

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