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Procedure to produce aromatic products and olefinic products of high added value from a fraction of petroleum containing aromatic compounds

机译:从一部分含芳烃化合物的石油生产高附加值芳烃产品和烯烃产品的程序

摘要

Process for producing aromatic products and olefinic products from a petroleum fraction containing an aromatic compound, comprising the steps of: (a) hydroprocessing a petroleum fraction containing an aromatic compound in the presence of a catalyst to partially saturate the components in the oil fraction; (b) performing the fluidized catalytic cracking of the partially saturated components in step (a) using a fluidized bed reactor with catalyst circulation capable of continuously regenerating an inactivated catalyst in the presence of a cracking catalyst, which is a spherical catalyst that comprises an amorphous solid acid including silica and alumina or comprising a molecular sieve of crystalline zeolite having a silica / alumina molar ratio of 300 or less and a pore size of 4~10Å (Angstrom); (c) separating the cracked components in step (b) into (i) benzene, toluene, xylene and aromatic components of 9 or more carbon atoms, (ii) olefin components and (iii) a residual petroleum fraction; and (d) carrying out the transalkylation of benzene, toluene and aromatic components of 9 or more carbon atoms separated in step (c).
机译:由含芳族化合物的石油馏分生产芳族产物和烯烃产物的方法,包括以下步骤:(a)在催化剂存在下加氢处理含芳族化合物的石油馏分,使油馏分中的组分部分饱和; (b)使用具有能够在裂化催化剂存在下连续地再生灭活的催化剂的催化剂循环的流化床反应器,在步骤(a)中对部分饱和的组分进行流化催化裂化,所述裂化催化剂是包含无定形的球形催化剂固体酸,包括二氧化硅和氧化铝,或包含二氧化硅/氧化铝摩尔比为300或更小且孔径为4〜10Å(埃)的结晶沸石的分子筛; (c)将步骤(b)中的裂化组分分离为(i)苯,甲苯,二甲苯和9个或更多个碳原子的芳族组分,(ii)烯烃组分和(iii)残余石油馏分; (d)进行在步骤(c)中分离的苯,甲苯和9个或更多个碳原子的芳族组分的烷基转移。

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