Polymer comprising repetitive units consisting of a substituted pyrrole ring and products obtained by combining said polymers with carbon allotropes

摘要

Polymer comprising repeating units of formula (I), ** Formula ** wherein if R 1, R 2, R 3, R 4 are independently selected from the group consisting of: hydrogen, C 1 -C 22 alkyl, alkenyl or alkynyl, linear alkyl or branched C2-C22, aryl, C1-C22 alkyl-aryl, alkenyl-aryl, linear C2-C22 alkynyl or C2-C22 branched-aryl, heteroaryl; then R is independently selected from the group consisting of: ** Formula ** wherein R5, R6, R7 are selected from the group consisting of: a straight or branched C1-C22 saturated or unsaturated hydrocarbon chain, a cyclic hydrocarbon chain C5- C6 unsubstituted or substituted, an aromatic group without heteroatoms unsubstituted or substituted by one or more linear or branched C1-C22 hydrocarbon chains, an aromatic group containing from 1 to 3 heteroatoms unsubstituted or substituted by one or more C1-C2 hydrocarbon chains C22 saturated or unsaturated linear or branched, or R6 is equal to zero; ** Formula ** wherein R8 is selected from: a C1-C22 linear or branched saturated or unsaturated hydrocarbon chain, a cyclic hydrocarbon chain C5-C6 unsubstituted or substituted, an aromatic group without heteroatoms or substituted with one or more C1-C22 linear or branched saturated or unsaturated hydrocarbon chains, an aromatic group containing heteroatom in a number of 1 to 3 unsubstituted or substituted with one or more linear or branched saturated or unsaturated C1-C22 hydrocarbon chains, or compounds of formula ** Formula wherein R9, R10, R11, R12 are independently selected of the group consisting of: hydrogen, C1-C22 alkyl or straight or branched C2-C22 alkenyl or alkynyl, aryl, straight or branched C2-C22 alkyl-aryl, straight or branched C2-C22 alkenyl-aryl, alkynyl (Linear or branched C2-C22) -aryl, heteroaryl n is an integer from 1 to 1000; if R is ** Formula ** wherein R13 and R14 are independently selected from the group consisting of: hydrogen, C1-C22 alkyl, straight or branched C2-C22 alkenyl or alkynyl, aryl, straight or branched C2-C22 alkyl; -aryl, straight or branched C2-C22 alkenyl-aryl, straight or branched C2-C22 alkynyl-aryl, heteroaryl; ** Formula ** or wherein R15 is independently selected from the group consisting of: a hydrocarbon chain C1-C3 saturated or unsaturated, linear or branched, a carbonyl group; then R1 and R4 are ** Formula ** wherein R16, R17 are independently selected from the group consisting of: hydrogen, C1-C3 alkyl, straight or branched C2-C22 alkenyl or alkynyl, aryl, linear or C1-C22 alkyl branched) -aryl, straight or branched C2-C22 alkenyl-aryl, straight or branched C2-C22 alkynyl-aryl, heteroaryl; m is an integer from 1 to 1000.