PREPARATION OF AROMATIC-SUBSTITUTED SILYLAMINES BY THE DEHYDROGENATIVE COUPLING OF AROMATIC-SUBSTITUTED AMINE N-H AND SI-H BONDS

摘要

The present disclosure is directed at methods of forming an N-Si silyl bond, the method comprising contacting an organic substrate comprising an aromatic amine having at least one N- H bond with a mixture comprising of (a) at least one hydrosilane or hydrosiloxane and (b) at least one hydroxide or alkoxide, under conditions sufficient to form the N-Si bond. The disclosure is further directed to the compositions involved in these methods and the products that result therefrom.