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SYSTEM AND METHOD FOR DESULFURIZATION AND DENITRIFICATION OF ALUMINA CALCINATION FLUE GAS, AND USE
SYSTEM AND METHOD FOR DESULFURIZATION AND DENITRIFICATION OF ALUMINA CALCINATION FLUE GAS, AND USE
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机译:氧化铝煅烧烟气脱硫脱硝的系统和方法及用途
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摘要
Disclosed are a system and a method for desulfurization and denitrification of an alumina calcination flue gas, and a use. The system comprises an ozone generator (1), a red mud pre-impregnation slurry scrubbing tower (3), and a red mud pre-impregnation tank (5) and a red mud pre-impregnation clear liquid scrubbing tower (10). NO x in a flue gas is oxidized into a high valence oxynitride by ozone, and with the red mud as an absorbent, the synergistic absorption of SO 2 and NO x in the flue gas is achieved, while the dealkalization of the red mud is achieved. By means of the synergistic catalytic oxidation of metal ions such as Fe 3+ in a red mud slurry and ozone, the synergistic absorption of sulfur and oxynitride is promoted and the material consumption of the subsequent desulfurization and denitrification is reduced; and the use of a structure of staged absorption in two towers overcomes the problem of the difficulty in absorbing NO 2 with a low O 3/NO X molar ratio by enhancing absorption with sodium alkali in a second stage tower, while decreasing the consumption of and risk of escape of the ozone, wherein same has the advantages of a high purification efficiency and a low operation cost, and has a stronger applicability to the alumina calcination flue gas.
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机译:公开了一种用于氧化铝煅烧烟道气的脱硫和反硝化的系统和方法,以及一种用途。该系统包括臭氧发生器(1),赤泥预浸渍浆料洗涤塔(3),赤泥预浸渍槽(5)和赤泥预浸渍透明液体洗涤塔(10)。烟气中的NO x Sub>被臭氧氧化为高价氮氧化物,以赤泥为吸收剂,协同吸收SO 2 Sub>和NO 烟气中的x Sub>得以实现,赤泥的脱碱得以实现。通过赤泥浆液中的金属离子(如Fe 3 + Sup>)和臭氧的协同催化氧化作用,促进了硫和氮氧化物的协同吸收,从而减少了后续脱硫和反硝化的材料消耗。减少并且在两个塔中采用分级吸收的结构克服了难以吸收低O 3 Sub> / NO X Sub的NO 2 Sub>的问题。通过提高第二级塔中碱钠的吸收,同时降低臭氧的消耗和逃逸的风险,从而具有大于摩尔比的优点,其中,具有净化效率高和运行成本低的优点,并且对臭氧的适用性更强。氧化铝煅烧烟气。
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