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METHOD OF CONVERTING A HEAVY HYDROCARBON FEEDSTOCK, INVOLVING SELECTIVE DE-ASPHALTING UPSTREAM FROM CONVERSION STEP

机译:转换重烃原料的方法,涉及从转化步骤中选择脱沥青的超级方法

摘要

FIELD: chemistry.;SUBSTANCE: invention relates to a method of converting a heavy hydrocarbon fraction having a boiling point of at least 300 °C. Method includes the following stages: a) at least one stage of selective deasphalting of heavy hydrocarbon feedstock by means of liquid extraction, providing separation of at least one asphalt fraction, at least one deasphalted oil fraction, wherein at least one of said deasphalting steps is carried out using a mixture of at least one polar solvent and at least one apolar solvent, wherein volume ratio of polar solvent in mixture of polar solvent and apolar solvent is from 0.1 to 95 %, wherein the polar solvent is selected from pure aromatic or naphthenic aromatic solvents, wherein the polar solvents contain hetero-elements or mixtures thereof. At that, the apolar solvent contains a solvent consisting of a saturated hydrocarbon containing a number of carbon atoms higher than or equal to 2, wherein deasphalting steps are carried out in subcritical conditions of used mixture of solvents. Temperature ranges from 50 to 350 °C, preferably from 90 to 320 °C, and pressure ranges from 0.1 to 6 MPa, b) one step of hydrofracturing the deasphalted oil fraction in the presence of hydrogen in at least one three-phase reactor, wherein said reactor contains at least one hydroconversion catalyst and operates in a fluidised bed with an upward flow of liquid and gas and comprises at least one catalyst discharge device from said reactor and at least one fresh catalyst feed device to said reactor, in conditions allowing to obtain an effluent stream containing a gas fraction containing for the most part H2 and H2S, and liquid fraction with reduced content of carbon according to Conradson, metals, sulphur and nitrogen, c) one step of separating the effluent from step b) to obtain a gas fraction containing for the most part a compound H2 and H2S, and a liquid fraction with reduced content of carbon according to Conradson, metals, sulphur and nitrogen.;EFFECT: use of the proposed invention increases flexibility and functionality of the raw material conversion scheme according to the invention.;21 cl, 6 tbl, 3 ex
机译:技术领域本发明涉及转化沸点至少为300℃的重质烃馏分的方法。该方法包括以下阶段:a)至少一个阶段,通过液体萃取对重质烃原料进行选择性脱沥青,提供至少一种沥青馏分,至少一种脱沥青油馏分的分离,其中至少一个所述脱沥青步骤为使用至少一种极性溶剂和至少一种非极性溶剂的混合物进行,其中极性溶剂在极性溶剂和非极性溶剂的混合物中的体积比为0.1%至95%,其中极性溶剂选自纯芳族或环烷类芳族溶剂,其中极性溶剂包含杂元素或它们的混合物。那时,非极性溶剂包含由包含碳原子数大于或等于2的数目的饱和烃组成的溶剂,其中脱沥青步骤在所用溶剂混合物的亚临界条件下进行。温度范围是50至350°C,最好是90至320°C,压力范围是0.1至6 MPa,b)在至少一个三相反应器中在氢气存在下将脱沥青油馏分加氢裂化的一步,其中所述反应器包含至少一种加氢转化催化剂,并在流化床中以向上的液体和气体流运行,并且在允许以下条件的条件下,包括至少一个从所述反应器排出的催化剂排出装置和至少一个向所述反应器进料的新鲜催化剂。根据Conradson的要求,获得一种废水流,该废水流的气体馏分包含大部分H 2 和H 2 S,以及根据Conradson,金属,硫和氮气; c)从步骤b)中分离出废水的步骤,以获得一种气体馏分,该气体馏分大部分包含化合物H 2 和H 2 S,以及一种液体根据Conradson,金属,硫和氮减少碳含量的馏分效果:所提出的发明的使用增加了根据本发明的原料转化方案的灵活性和功能性; 21 cl,6 tbl,3 ex

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