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METHOD OF PURIFYING LIQUEFIED HYDROCARBON GASES FROM MOLECULAR SULPHUR, SULPHUR COMPOUNDS AND CARBON DIOXIDE

机译:从分子硫,硫化合物和二氧化碳中纯化液化气的方法

摘要

FIELD: technological processes.;SUBSTANCE: invention can be used in oil, gas, gas processing, oil refining, petrochemical, chemical and other industries. Method comprises mixing liquefied hydrocarbon gases, which are a hydrocarbon liquid, with an absorbent containing sulphides and / or polysulphides, to form, after completion of mixing, a two-phase layer consisting of an absorbent aqueous layer containing said components extracted from the purified hydrocarbon liquid, and a layer of purified hydrocarbon fluid with reduced content of said components. Absorbent used is an aqueous solution of ethanolamine with concentration of 18–72 wt%, containing water-soluble sulphides and / or polysulphides, selected from: sulphides and / or polysulphides of alkali, alkali-earth metals, ammonium, as well as ethanolamines, wherein content of sulphides and / or polysulphides in water solution of ethanolamine is not less than 0.05 wt%. Mixing of liquefied hydrocarbon gases with absorbent is carried out in an amount required for formation after completion of mixing of absorbent water layer, containing molecular sulphur extracted from purified hydrocarbon liquid, sulphur compounds and carbon dioxide, and a layer of hydrocarbon fluid with no or low content of molecular sulphur, sulphur compounds and carbon dioxide, which is then decanted from the aqueous layer of the absorbent to obtain a purified product.;EFFECT: high efficiency of extracting molecular sulphur simultaneously with sulphur compounds and carbon dioxide to obtain a product purified to required standards, as well as reducing capital and operating costs.;4 cl, 8 tbl, 8 ex
机译:领域:工艺流程;物质:发明可用于石油,天然气,天然气加工,炼油,石油化工,化学等行业。该方法包括将作为烃液体的液化烃气体与含有硫化物和/或多硫化物的吸收剂混合,以在混合完成之后形成两相层,该两相层由吸收剂水层组成,该吸收剂水层包含从纯化的烃中提取的所述组分。液体和一层纯净的碳氢化合物流体,其中所述成分的含量降低。所使用的吸收剂为浓度为18-72 wt%的乙醇胺水溶液,其中包含水溶性硫化物和/或多硫化物,选自:碱金属,碱土金属,铵的硫化物和/或多硫化物以及乙醇胺,其中乙醇胺水溶液中的硫化物和/或多硫化物的含量不少于0.05重量%。液化烃气体与吸收剂的混合应在吸收剂水层完成混合之后形成,该吸收剂水层包含从纯化烃液体中提取的分子硫,硫化合物和二氧化碳,以及不含有或含有少量烃的烃类流体层分子硫,硫化合物和二氧化碳的含量,然后将其从吸收剂的水层中倾析出来,以获得纯化的产品;效果:高效地与硫化合物和二氧化碳同时萃取分子硫以获得纯化为所需的标准,以及降低资本和运营成本。; 4 cl,8 tbl,8 ex

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