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WATER-STABLE CATALYSTS FOR POLYURETHANE MANUFACTURE

机译:聚氨酯生产的水稳催化剂

摘要

A method of manufacturing a polyurethane compound comprises mixing together a polyol, a polyisocyanate compound and a catalyst and allowing the mixture to cure to form a polyurethane, and is characterized in that the catalyst is a neutral complex of a metal selected from Ti, Zr, Hf, Al, Fe, Bi or Sn and a multidentate organic ligand having: a) a number of anionic donor sites=x; b) a number of neutral donor sites, capable of forming a co-ordinate bond with the metal, =y; c) where x+y=from 5 to 8; d) x is from 2 to 4; e) the ligand molecule is of a size and conformation to enable each of the anionic donor sites and neutral donor sites to form a bond with the same metal atom.
机译:一种制造聚氨酯化合物的方法,该方法包括将多元醇,多异氰酸酯化合物和催化剂混合在一起并使其固化以形成聚氨酯,其特征在于催化剂是选自Ti,Zr, Hf,Al,Fe,Bi或Sn和具有以下特征的多齿有机配体:a)多个阴离子供体位= x; b)能够与金属形成配位键的许多中性施主部位= y; c)其中x + y = 5至8; d)x是2到4; e)配体分子具有一定的大小和构象,以使每个阴离子供体位点和中性供体位点能够与相同的金属原子形成键。

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