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EXTRACTION OF RARE EARTH ELEMENTS WITH DEEP EUTECTIC SOLVENTS

机译:用深共熔溶剂萃取稀土元素

摘要

It relates to process for the extraction of rare earth elements from a starting product containing them in metal or alloy form which comprises: a) contacting the starting product containing rare earth elements in metal or alloy form with a deep eutectic solvent that consists of a mixture of a hydrogen bond acceptor (HBA) compound (A) selected from a salt of the formula Cat + X - (I), betaine or a salt thereof, and carnitine or a salt thereof; and a hydrogen bond donor (HBD) compound (B) in a molar ratio of (A) to (B) from 1:10 to 10:1, wherein the deep eutectic solvent is capable of extracting at least 50% w/w of one or more rare earth elements contained in the starting solid product in less than 5 hours, and b) separating the solvent containing the rare earth elements in dissolution from the undissolved solid.
机译:本发明涉及从包含金属或合金形式的稀土元素的起始产物中提取稀土元素的方法,该方法包括:a)使包含金属或合金形式的稀土元素的起始产物与由混合物组成的深共熔溶剂接触。选自式Cat + X-(I)的盐,甜菜碱或其盐以及肉碱或其盐的氢键受体(HBA)化合物(A); (H)与(B)的摩尔比为1:10至10:1的氢键供体(HBD)化合物(B),其中深共晶溶剂能够提取至少50%w / w的在少于5小时内在起始固体产物中包含一种或多种稀土元素,并且b)将溶解中包含稀土元素的溶剂与未溶解固体分离。

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