首页> 外国专利> MODIFIED Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR, HYDROCRACKING CATALYST AND PREPARATION METHOD THEREFOR, AND METHOD FOR HYDROCRACKING HYDROCARBON OIL

MODIFIED Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR, HYDROCRACKING CATALYST AND PREPARATION METHOD THEREFOR, AND METHOD FOR HYDROCRACKING HYDROCARBON OIL

机译:改进的y型分子筛及其制备方法,加氢裂化催化剂和制备方法以及加氢裂解烃油的方法

摘要

The present disclosure relates to the technical field of hydrocracking, and discloses a modified Y-type molecular sieve and process for preparing same, a hydrocracking catalyst and preparation method thereof, and a method for hydrocracking a hydrocarbon oil. The modified Y-type molecular sieve contains 0.5-2 wt.% of Na2O based on the total amount of the modified Y-type molecular sieve; the ratio between the total acid amount measured by pyridine and infrared spectrometry of the modified Y-type molecular sieve and total acid amount measured by n-butyl pyridine and infrared spectrometry of the modified Y-type molecular sieve is 1-1.2; the total acid amount measured by pyridine and infrared spectrometry of the modified Y-type molecular sieve is 0.1-1.2 mmol/g. The acid center sites of the molecular sieve of the modified Y-type molecular sieve are intensively distributed in the large pore channels, the molecular sieve is used in the hydrocracking reaction process of a wax oil, which is beneficial to enhancing reaction selectivity of the macromolecular cyclic hydrocarbons in the wax oil, reducing the occurrence of secondary cracking reaction, improving quality of hydrocracking tail oil, and increasing yield of the reaction liquid products.
机译:本发明涉及加氢裂化技术领域,公开了一种改性Y型分子筛及其制备方法,加氢裂化催化剂及其制备方法和加氢裂化烃油的方法。所述改性Y型分子筛基于所述改性Y型分子筛的总量为0.5-2重量%的Na 2 O。改性Y型分子筛的吡啶和红外光谱测定的总酸量与改性Y型分子筛的正丁基吡啶和红外光谱测定的总酸量之比为1-1.2。改性Y型分子筛通过吡啶和红外光谱法测得的总酸量为0.1-1.2mmol / g。改性Y型分子筛分子筛的酸中心位置集中分布在大孔道中,该分子筛用于蜡油的加氢裂化反应过程,有利于提高大分子的反应选择性。蜡油中的环状烃,减少了二次裂化反应的发生,提高了加氢裂化尾油的质量,并提高了反应液产品的收率。

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