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SURFACE PLASMON ENHANCED PHOTOCATALYSIS

机译:表面等离子体增强的光催化

摘要

Plasmonically-enhanced catalytic surfaces and accompanying optics are described herein. These elements facilitate efficient coupling of light energy into a photocatalytic system by way of a surface plasmon. Various compatible optical configurations are presented, with an emphasis on the broadband coupling of light into a single plasmon mode. In an example embodiment, dispersive optics are used to direct polychromatic light onto a grating-embossed SPR-active surface. Dispersive optics allow resonance to be achieved at a wide range of incident wavelengths. Energy then transfers from the excited plasmon to an adjacent photocatalyst. The plasmon mode thus acts as a "funnel" of broadband light energy to the catalytic materials. High-efficiency incoupling and outcoupling from the plasmon mode suggest overall enhancement of catalytic activity, and broad applicability is anticipated due to the inherent flexibility of the system. The catalytic surfaces and optical components can be fabricated as sheets or 3D arrays, justifying industrial-scale manufacturing.
机译:本文中描述了等离子体增强的催化表面和随附的光学器件。这些元素有利于通过表面等离子体激元将光能有效地耦合到光催化系统中。提出了各种兼容的光学配置,重点是将光宽带耦合到单个等离子体激元模式。在示例实施例中,色散光学器件用于将多色光引导到光栅压印的SPR有源表面上。色散光学器件可以在很宽的入射波长范围内实现共振。能量然后从激发的等离子体激元转移到相邻的光催化剂。因此,等离子体激元模式充当了宽带光能到催化材料的“漏斗”。从等离激元模式的高效耦合和外耦合表明催化活性的整体增强,并且由于该系统固有的灵活性,预计可广泛应用。催化表面和光学组件可以制成薄片或3D阵列,从而证明了工业规模的制造合理性。

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