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Integrated energy and environment method for producing aromatic dicarboxylic acids by oxidation

机译:氧化法合成芳族二羧酸的能源与环境综合方法

摘要

A continuous process for oxidizing a di-alkyl-substituted aromatic compound with compressed air in a primary bubble column reactor, the process comprising the steps of: Transferring the post-oxidized reaction medium to overhead gas and underflow slurry; collecting overhead gas from the oxidation reactor and degassing unit and combining the combined overhead gas into a water removal tower (WRC) Transporting the underflow slurry from the degassing unit to the digestion unit for further oxidation without adding air to the digestion unit; moving overhead gas to the water removal tower; final oxidized slurry Crystallizing the slurry; and filtering the slurry through a rotary pressure filter. At that time, involves using some of the energy of the exhaust gas from the WRC, to drive the air compressor for supplying compressed air for oxidation.
机译:在初级鼓泡塔反应器中用压缩空气氧化二烷基取代的芳族化合物的连续方法,该方法包括以下步骤:将后氧化的反应介质转移到塔顶气体和底流淤浆中;从氧化反应器和脱气单元收集塔顶气体,并将合并的塔顶气体合并到脱水塔(WRC)中,将底流浆液从脱气单元输送到消化单元以进一步氧化,而无需向消化单元添加空气;将塔顶气体移至脱水塔;最终氧化的浆液使浆液结晶;通过旋转压力过滤器过滤浆料。当时,涉及使用来自WRC的部分废气能量来驱动空气压缩机,以供应压缩空气进行氧化。

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