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Inorganic monodisperse spherical fine particles, method for producing inorganic monodisperse spherical fine particles, battery electrode and battery

机译:无机单分散球形微粒,无机单分散球形微粒的制造方法,电池电极及电池

摘要

PROBLEM TO BE SOLVED: To provide inorganic monodisperse spherical fine particles which are characterized in that diameters thereof are 10 nm to 5 μm and they have a spinel type crystal structure, and to provide a production method thereof.SOLUTION: In a membrane emulsification process in which anode oxidation porous alumina having a hole array structure comprising arrangement of pores with uniform sizes in nanometer scale is used as an emulsification membrane, an aqueous solution in which a metal salt is dissolved in addition to a water-soluble monomer or oligomer and a polymerization initiator is used as a dispersion phase, and an oil phase to which a surfactant is added is used as a continuous phase. Precursor fine particles are produced by extruding the dispersion phase into the continuous phase via the porous alumina membrane so as to form liquid droplets, and subsequently polymerizing and solidifying the obtained liquid droplets. Spherical fine particles having a spinel type crystal structure can be produced by subjecting the obtained precursor fine particles to calcination treatment as post treatment.SELECTED DRAWING: None
机译:解决的问题:提供特征在于其直径为10nm至5μm并且具有尖晶石型晶体结构的无机单分散球形细颗粒,并提供其制备方法。解决方案:在膜乳化过程中具有孔阵列结构的阳极氧化多孔氧化铝被用作乳化膜,该阳极氧化多孔氧化铝具有包含纳米尺寸的均一尺寸的孔的排列的孔阵列结构,除水溶性单体或低聚物之外还溶解有金属盐的水溶液和聚合引发剂用作分散相,加有表面活性剂的油相用作连续相。通过将分散相经由多孔氧化铝膜挤出到连续相中以形成液滴,然后聚合并固化所获得的液滴,来制备前体微粒。通过对所得的前体微粒进行后处理的煅烧处理,可以制造出具有尖晶石型晶体结构的球状微粒。

著录项

  • 公开/公告号JP6749574B2

    专利类型

  • 公开/公告日2020-09-02

    原文格式PDF

  • 申请/专利权人 東京都公立大学法人;

    申请/专利号JP20150150180

  • 发明设计人 益田 秀樹;柳下 崇;

    申请日2015-07-29

  • 分类号C01G53;C01G51;H01M4/48;

  • 国家 JP

  • 入库时间 2022-08-21 11:33:43

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