首页> 外国专利> A method of forming an antifouling coating film on the surface of a ship using an antifouling coating composition containing a copolymer and an antifouling agent.

A method of forming an antifouling coating film on the surface of a ship using an antifouling coating composition containing a copolymer and an antifouling agent.

机译:一种使用包含共聚物和防污剂的防污涂料组合物在船舶表面上形成防污涂膜的方法。

摘要

The present invention provides a composition for forming an antifouling coating film which has high environmental safety, and which is able to maintain coating film dissolution for a long period of time even after being exposed to sunlight for a long period of time, thereby being capable of exhibiting good antifouling performance even at the water line part to which aquatic fouling organisms are likely to adhere. The present invention provides an antifouling coating composition which contains a copolymer A, a copolymer B and an antifouling agent, and which is configured such that: the copolymers A and B are obtained by respectively copolymerizing a mixture of a monomer (a) and a polymerizable unsaturated monomer (b) other than the monomer (a); the monomer (a) is represented by formula (1) (wherein R1 represents a hydrogen atom or a methyl group; and R2, R3 and R4 are selected from among a phenyl group and branched alkyl groups having 3-8 carbon atoms, and may be same as or different from each other); the copolymer A satisfies the requirements (A1) and (A2) described below; the copolymer B satisfies the requirements (B1) and (B2) described below; and the content of the copolymer A relative to the total mass of the copolymer A and the copolymer B is 5-45% by mass. (A1) The content of a compound, in which R1 is a hydrogen atom, in the monomer (a) relative to the total mass of the monomer (a) and the monomer (b) is 30-80% by mass. (A2) The content of 2-methoxyethyl acrylate in the monomer (b) relative to the total mass of the monomer (a) and the monomer (b) is 5-30% by mass. (B1) The content of a compound, in which R1 is a methyl group, in the monomer (a) relative to the total mass of the monomer (a) and the monomer (b) is 30-80% by mass. (B2) The content of 2-methoxyethyl methacrylate in the monomer (b) relative to the total mass of the monomer (a) and the monomer (b) is 15-50% by mass.
机译:本发明提供一种环境安全性高的防污涂膜形成用组合物,即使长时间暴露于阳光下也能够长时间保持涂膜溶解,从而能够形成防污涂膜。即使在水垢生物可能附着的水线部分也显示出良好的防污性能。本发明提供一种防污涂料组合物,其包含共聚物A,共聚物B和防污剂,并且其构造使得:共聚物A和B分别通过使单体(a)和可聚合单体的混合物共聚而获得。单体(a)以外的不饱和单体(b);单体(a)由式(1)表示(其中R 1代表氢原子或甲基;并且R 2,R 3和R 4选自苯基和具有3-8个碳原子的支链烷基,并且可以彼此相同或不同);共聚物A满足下述条件(A1)和(A2)。共聚物B满足下述(B1)和(B2)的条件。相对于共聚物A和共聚物B的总质量,共聚物A的含量为5〜45质量%。 (A1)相对于单体(a)和单体(b)的总质量,单体(a)中R 1为氢原子的化合物的含量为30〜80质量%。 (A2)相对于单体(a)和单体(b)的总质量,单体(b)中丙烯酸2-甲氧基乙基酯的含量为5〜30质量%。 (B1)相对于单体(a)和单体(b)的总质量,单体(a)中R 1为甲基的化合物的含量为30〜80质量%。 (B2)相对于单体(a)和单体(b)的总质量,单体(b)中的甲基丙烯酸2-甲氧基乙酯的含量为15〜50质量%。

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