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BLOCK COPOLYMER HYDRIDE AND MANUFACTURING METHOD OF BLOCK COPOLYMER HYDRIDE

机译:嵌段共聚物氢化物及其制备方法

摘要

To provide block copolymer hydride capable of molding a molded body high in heat resistance and high in adhesiveness to a molded body consisting of cyclic olefin ring-opening polymer hydride (COP).SOLUTION: There is provided block copolymer hydride [D] by hydrogenation of a block copolymer [C] consisting of at least 2 polymer blocks [A] mainly containing an aromatic vinyl monomer unit derived from an aromatic vinyl compound, and at least one polymer block [B] mainly containing a chain conjugated diene monomer unit derived from a chain conjugated diene compound, an elution curve measured by gel permeation chromatography (GPC) has at least 2 block copolymer hydride derived peaks (A and B in elution order), a ratio of detection sensitivity (mV) of the peak A to detection sensitivity of the peak B is 1.5 to 9.0, and standard polystyrene converted molecular weight based on elution time of the peak B is 5000 or more.SELECTED DRAWING: Figure 1
机译:提供一种嵌段共聚物氢化物,其能够模制高耐热性和对由环状烯烃开环聚合物氢化物(COP)组成的模制体的高粘附性的溶液。解决方案:提供一种通过氢化氢化而制备的嵌段共聚物氢化物[D]。嵌段共聚物[C],其由至少2个主要包含衍生自芳族乙烯基化合物的芳族乙烯基单体单元的聚合物嵌段[A]和至少一个主要包含衍生自α-烯烃的链状共轭二烯单体单元的聚合物嵌段[B]组成链共轭二烯化合物,通过凝胶渗透色谱(GPC)测量的洗脱曲线具有至少两个嵌段共聚物氢化物衍生的峰(洗脱顺序为A和B),峰A的检测灵敏度(mV)与峰B为1.5至9.0,基于峰B洗脱时间的标准聚苯乙烯换算分子量为5000或更高。

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