An environmental control system includes a carbon dioxide source; a compressor downstream of the carbon dioxide source; a Sabatier reactor downstream of the compressor, wherein the Sabatier reactor reacts carbon dioxide with hydrogen to produce methane and water; a water separator downstream of the Sabatier reactor, wherein the water separator separates hydrocarbons from water, wherein the hydrocarbons include methane; a pyrolysis assembly downstream of the water separator and upstream of the compressor, wherein the pyrolysis assembly pyrolyzes methane to produce carbon and hydrogen, wherein the pyrolysis assembly includes a pre-form that adheres carbon; and an oxygen generating assembly (OGA) downstream of the water separator and upstream of the compressor, wherein the OGA converts water to hydrogen and oxygen.
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