A pen structure with a glass smasher has the glass smasher mounted at the front end of a pen. When a user holds the pen and presses the front end (i.e., the smashing cone) of the smashing rod of the glass smasher forcibly against a glass obstacle, an impact block will strike the rear section of the smashing rod vigorously such that the smashing cone is instantly driven to smash the glass obstacle. A ballpoint/rollerball refill is detachably provided in the pen and is at least 6 cm long in order to contain enough ink. The overall length of the pen is at least 10 cm so that the pen can be easily held while the user writes or draws with the ballpoint/rollerball tip and while the user applies a force to a glass obstacle through the front end of the smashing rod to smash the glass obstacle.
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