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Catalytic composition comprising nickel and a phosphine-type ligand, and use thereof in an olefin oligomerisation method
Catalytic composition comprising nickel and a phosphine-type ligand, and use thereof in an olefin oligomerisation method
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机译:包含镍和膦类配体的催化组合物及其在烯烃低聚方法中的用途
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摘要
A process for the dimerization of ethylene to 1-butene, carried out with a catalytic composition comprising: at least one nickel precursor with an oxidation number of (+II), at least one phosphine ligand with formula PR1R2R3 in which the groups R1, R2 and R3 may be identical or different and which may or may not be bonded together, and at least one activating agent selected from the group formed by chlorinated and brominated hydrocarbylaluminium compounds, used alone or as a mixture, the composition having a molar ratio of the phosphine ligand to the nickel precursor in the range 5 to 30 and a molar ratio of the activating agent to the phosphine ligand greater than or equal to 1.
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机译:一种乙烯二聚为1-丁烯的方法,该催化剂组合物包括:至少一种氧化数为(+ II)的镍前体,至少一种式PR 1 Sub的膦配体> R 2 Sub> R 3 Sub>,其中组R 1 Sub>,R 2 Sub>和R 3 子可以相同或不同并且可以结合或可以不结合在一起,并且至少一种选自氯化和溴化烃基铝化合物形成的组的活化剂可以单独使用或作为混合物使用,所述组合物具有镍前体的膦配体在5至30的范围内,活化剂与膦配体的摩尔比大于或等于1。
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