SELF-REINFORCED CEMENTITIOUS COMPOSITE COMPOSITIONS FOR BUILDING-SCALE THREE DIMENSIONAL (3D) PRINTING

摘要

Printable cementitious compositions for additive manufacturing are provided, that have a fresh state and a hardened state. In fresh state, the composition is flowable and extrudable in the additive manufacturing process. In the hardened state, the composition exhibits strain hardening. In one variation, the strain hardening is represented by a uniaxial tensile strength of ≥about 2.5 MPa, a tensile strain capacity of ≥about 1%, and a compressive strength at 100 hours of ≥about 20 MPa. In other variations, the composition includes Portland cement, a calcium aluminate cement, a fine aggregate, water, a high range water reducing agent (HRWRA), and a polymeric fiber, as well as one or more optional components selected from: fly ash, silica flour, microsilica, attapulgite nanoclay, and/or hydroxypropylmethyl cellulose (HPMC). Methods of additive manufacturing with such compositions are also provided.