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methods for removing impurities from a hydrocarbon stream and their use in aromatic alkylation processes

机译:烃物流中去除杂质的方法及其在芳族烷基化工艺中的用途

摘要

the present invention relates to methods for removing impurities from a hydrocarbon stream using a protective bed material. the protective bed material includes compositions comprising a zeolite and a support or mesoporous binder. zeolite has a restriction index less than 3. the support or meiosporous binder comprises a mesoporous metal oxide that has a particle diameter greater than or equal to 20 µm at 50% of the cumulative pore size distribution (d50), a pore volume less than 1 cm³ / g and an alumina content greater than 75% by weight. processes for producing monoalkylated aromatic compounds (e.g., ethylbenzene or cumene) are also described with the use of impure feed streams that are treated by the methods described to remove impurities that act as catalyst poisons for downstream alkylation and / or transalkylation catalysts .
机译:本发明涉及使用保护床材料从烃流中除去杂质的方法。保护床材料包括包含沸石和载体或中孔粘合剂的组合物。沸石的限制指数小于3。载体或介孔粘合剂包含介孔金属氧化物,其在50%的累积孔径分布(d50)时具有大于或等于20 µm的粒径,孔径小于1立方厘米/克,氧化铝含量大于75%(重量)。还描述了使用不纯的进料流来生产单烷基化的芳族化合物(例如乙苯或枯烯)的方法,所述不纯的进料流通过所述方法处理以除去杂质,所述杂质充当下游烷基化和/或烷基转移催化剂的催化剂毒物。

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