OXIDANT COMPOSITION, PROCESS TO OXIDATE A SUBSTRATE AND METHOD TO GENERATE AN OXIDANT ELECTROPHILE

摘要

an oxidizing composition is provided, in which a liquid medium is substantially inert in the presence of an oxidizing electrophile contained in the liquid medium. the composition comprises (a) an oxidizing electrophile comprising an element of the main group in oxidized form and at least one conjugated anion of an oxygenated acid; (b) a non-oxidizable liquid selected from a fluorinated hydrocarbon, a sulfone, a deactivated arene, a deactivated aliphatic, a deactivated heteroarene, a deactivated heteroaliphatic and a combination thereof; and (c) optionally one or more salt additives. furthermore, a method is provided for using the oxidizing composition to oxidize a substrate and a method for generating and / or regenerating an oxidizing electrophile comprising an element of the main group.