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2,6-Diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer having adsorption properties

机译:具有吸附性能的2,6-二乙酰基吡啶双(异烟酰酰肼基)(2-)钴(II)-水(1 / 5.75)配位聚合物

摘要

The invention relates to coordination chemistry, namely to a coordination polymer of cobalt(II) with the Schiff base - 2,6-diacetylpyridine bis(isonicotinoylhydrazone), which has adsorption properties.According to the invention, claimed is 2,6-diacetylpyridinebis(isonicotinoylhydrazonato)(2-)cobalt(II)-water(1/5.75) coordination polymer of the formula {[Co(L)]·5.75H2O}n, produced in solvothermal conditions at a temperature of 120°C, for 48 hours, in a dimethylformamide/methanol solvent mixture. The polymer has a porous structure with a specific surface of 841 m2/g calculated according to the BET equation and has adsorption properties.
机译:本发明涉及配位化学,即钴(II)与席夫碱的配位聚合物-具有吸附性能的2,6-二乙酰基吡啶双(异烟酰胺基hydr)。根据本发明,要求保护的是2,6-二乙酰基吡啶二(在溶剂热条件下于120°C的温度下生产48小时的式{[Co(L)]·5.75H2O} n的异烟酰基酰肼基)(2-)钴(II)-水(1 / 5.75)配位聚合物在二甲基甲酰胺/甲醇溶剂混合物中。该聚合物具有根据BET方程计算的比表面积为841m2​​ / g的多孔结构,并具有吸附性能。

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