ENHANCED LIGHT OLEFIN YIELD VIA STEAM CATALYTIC DOWNER PYROLYSIS OF HYDROCARBON FEEDSTOCK

摘要

WO 18/ 20065 0 Al oxen Awr 708-, 114- r' 16-, 12 1 . 24 7 22 - 1 0 up now 06 726 FIG. 1 (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 01 November 2018 (01.11.2018) WIPO PCT Hu onus ono o 111°1°1111H ioo lio Elio oimIE (10) International Publication Number WO 2018/200650 Al (51) International Patent Classification: ClOG 9/28 (2006.01) ClOG 11/20 (2006.01) ClOG 11/16 (2006.01) (21) International Application Number: PCT/US2018/029325 (22) International Filing Date: 25 April 2018 (25.04.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/489,681 25 April 2017 (25.04.2017) US (71) Applicant: SAUDI ARABIAN OIL COMPANY [SA/SA]; 1 Eastern Avenue, Dhahran, 31311 (SA). (71) Applicant (for AG only): ARAMCO SERVICES COM- PANY [US/US]; 9009 West Loop South, Houston, TX 77096 (US). (72) Inventors: AL-GHRAMI, Musaed, Salem; Saudi Arabian Oil Company, P.O. Box 10587 - Saudi Aramco, Dhahran, 31311 (SA). XU, Wei; Saudi Arabian Oil Company, P.O. Box 13495 - Saudi Aramco, Dhahran, 31311 (SA). AKAH, Aaron, Chi; Saudi Arabian Oil Company, P.O. Box 8741 - Saudi Aramco, Dhahran, 31311 (SA). (74) Agent: RHEBERGEN, Constance, Gall; Bracewell LLP, P.O. Box 61389, Houston, TX 77208-1389 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). = (54) Title: ENHANCED LIGHT OLEFIN YIELD VIA STEAM CATALYTIC DOWNER PYROLYSIS OF HYDROCARBON FEEDSTOCK (57) : Systems and methods for steam and catalytic cracking of a hydrocarbon inlet stream comprising hydrocarbons. Systems and methods can include a catalyst feed stream, where the catalyst feed stream comprises a fluid and a heterogeneous catalyst, the heterogeneous catalyst operable to catalyze cracking of the hydrocarbons on surfaces of the heterogeneous cat- 0 2 alyst a steam feed stream, where the steam feed stream is operable to effect steam cracking of the hydrocarbons, and where the steam feed stream de- creases coking of the heterogeneous catalyst; and a downflow reactor, where the downflow reactor is operable to accept and mix the hydrocarbon inlet stream, the catalyst feed stream, and the steam feed stream, where the down- 18 flow reactor is operable to produce light olefms by steam cracking and cat- alytic cracking, and where the downflow reactor is operable to allow the het- 4 erogenous catalyst to flow downwardly by gravity. [Continued on next page] WO 2018/200650 Al MIDEDIM01101 DIDIREIE00101011111111111101111111111111111111 Published: — with international search report (Art. 21(3))